Quantifying Rival Bond Fission Probabilities following photoexcitation: C-S bond fission in t-butylmethylsulfide

Experimental data sets for the uv photodissociation of t-butylmethylsulfide measured by single photon ionisation coupled to multi-mass VMI. Theoretical calculations of cuts along relevant coordinates of potential energy surfaces and single point vibrational calculations of asymptotic products and parent molecules.