1,8-BIS(DIPHENYLPHOSPHINO)NAPHTHALENE - A RIGID CHELATING, DIPHOSPHINE ANALOG OF PROTON SPONGE

R D  JACKSON; S  JAMES; A G  ORPEN; P G  PRINGLE

1,8-BIS(DIPHENYLPHOSPHINO)NAPHTHALENE - A RIGID CHELATING, DIPHOSPHINE ANALOG OF PROTON SPONGE

R D JACKSON, S JAMES, A G ORPEN, P G PRINGLE

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Abstract

The synthesis of the new diphosphine, 1,8-bis(diphenylphosphino) naphthalene (1a), and its X-ray crystal structure are reported. Protonation of 1a gives a fluxional species to which a P-P bonded structure is assigned. Despite the strain apparent in the solid state due to the proximity of the diphenylphosphino groups, it appears that 1a has a normal coordination chemistry with platinum(II) and palladium(II).

Original language	English
Pages (from-to)	C3-C4
Number of pages	2
Journal	Journal of Organometallic Chemistry
Volume	458
Issue number	1-2
Publication status	Published - 5 Oct 1993

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Inorganic & Materials

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title = "1,8-BIS(DIPHENYLPHOSPHINO)NAPHTHALENE - A RIGID CHELATING, DIPHOSPHINE ANALOG OF PROTON SPONGE",

abstract = "The synthesis of the new diphosphine, 1,8-bis(diphenylphosphino) naphthalene (1a), and its X-ray crystal structure are reported. Protonation of 1a gives a fluxional species to which a P-P bonded structure is assigned. Despite the strain apparent in the solid state due to the proximity of the diphenylphosphino groups, it appears that 1a has a normal coordination chemistry with platinum(II) and palladium(II).",

author = "JACKSON, \{R D\} and S JAMES and ORPEN, \{A G\} and PRINGLE, \{P G\}",

year = "1993",

month = oct,

day = "5",

language = "English",

volume = "458",

pages = "C3--C4",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1-2",

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TY - JOUR

T1 - 1,8-BIS(DIPHENYLPHOSPHINO)NAPHTHALENE - A RIGID CHELATING, DIPHOSPHINE ANALOG OF PROTON SPONGE

AU - JACKSON, R D

AU - JAMES, S

AU - ORPEN, A G

AU - PRINGLE, P G

PY - 1993/10/5

Y1 - 1993/10/5

N2 - The synthesis of the new diphosphine, 1,8-bis(diphenylphosphino) naphthalene (1a), and its X-ray crystal structure are reported. Protonation of 1a gives a fluxional species to which a P-P bonded structure is assigned. Despite the strain apparent in the solid state due to the proximity of the diphenylphosphino groups, it appears that 1a has a normal coordination chemistry with platinum(II) and palladium(II).

AB - The synthesis of the new diphosphine, 1,8-bis(diphenylphosphino) naphthalene (1a), and its X-ray crystal structure are reported. Protonation of 1a gives a fluxional species to which a P-P bonded structure is assigned. Despite the strain apparent in the solid state due to the proximity of the diphenylphosphino groups, it appears that 1a has a normal coordination chemistry with platinum(II) and palladium(II).

M3 - Article (Academic Journal)

SN - 0022-328X

VL - 458

SP - C3-C4

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

1,8-BIS(DIPHENYLPHOSPHINO)NAPHTHALENE - A RIGID CHELATING, DIPHOSPHINE ANALOG OF PROTON SPONGE

Abstract

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