4,4'-bipyridyl adduct of an iodoantimonate anion linked by a 4,4'-bipypridium cation

JPH Charmant; NC Norman; AG Orpen; J Starbuck

doi:10.1107/S1600536803022347

4,4'-bipyridyl adduct of an iodoantimonate anion linked by a 4,4'-bipypridium cation

JPH Charmant, NC Norman, AG Orpen, J Starbuck

Research output: Contribution to journal › Article (Academic Journal) › peer-review

6 Citations (Scopus)

Abstract

The crystal structure of the title iodoantimonate complex, 4,4′-bipyridinium(2+) di-μ-iodo-bis[(4,4′-bipyridyl)triiodoantimony(III)], formulated as [4,4′-H₂bipy]²⁺[Sb₂I₈(4,4′-bipy)₂]²⁻ or (C₁₀H₁₀N₂)[Sb₂I₈(C₁₀H₈N₂)₂], contains layers of hydrogen-bonded ribbon polymers in which anionic dimetal complexes are linked through hydrogen bonding with 4,4′-H₂bipy cations. The complex is isostructural with its bismuth analogue.

Translated title of the contribution	4,4'-bipyridyl adduct of an iodoantimonate anion linked by a 4,4'-bipypridium cation
Original language	English
Pages (from-to)	m997-m999
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	11
DOIs	https://doi.org/10.1107/S1600536803022347
Publication status	Published - 2003

Bibliographical note

Other: This is an online journal

Access to Document

10.1107/S1600536803022347

Handle.net

Persistent link

Cite this

@article{117f536856bf4181aa872e413103e477,

title = "4,4'-bipyridyl adduct of an iodoantimonate anion linked by a 4,4'-bipypridium cation",

abstract = "The crystal structure of the title iodoantimonate complex, 4,4′-bipyridinium(2+) di-μ-iodo-bis[(4,4′-bipyridyl)triiodoantimony(III)], formulated as [4,4′-H2bipy]2+[Sb2I8(4,4′-bipy)2]2− or (C10H10N2)[Sb2I8(C10H8N2)2], contains layers of hydrogen-bonded ribbon polymers in which anionic dimetal complexes are linked through hydrogen bonding with 4,4′-H2bipy cations. The complex is isostructural with its bismuth analogue.",

author = "JPH Charmant and NC Norman and AG Orpen and J Starbuck",

note = "Other: This is an online journal",

year = "2003",

doi = "10.1107/S1600536803022347",

language = "English",

volume = "59",

pages = "m997--m999",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "Munksgaard International Publishers",

number = "11",

}

TY - JOUR

T1 - 4,4'-bipyridyl adduct of an iodoantimonate anion linked by a 4,4'-bipypridium cation

AU - Charmant, JPH

AU - Norman, NC

AU - Orpen, AG

AU - Starbuck, J

N1 - Other: This is an online journal

PY - 2003

Y1 - 2003

N2 - The crystal structure of the title iodoantimonate complex, 4,4′-bipyridinium(2+) di-μ-iodo-bis[(4,4′-bipyridyl)triiodoantimony(III)], formulated as [4,4′-H2bipy]2+[Sb2I8(4,4′-bipy)2]2− or (C10H10N2)[Sb2I8(C10H8N2)2], contains layers of hydrogen-bonded ribbon polymers in which anionic dimetal complexes are linked through hydrogen bonding with 4,4′-H2bipy cations. The complex is isostructural with its bismuth analogue.

AB - The crystal structure of the title iodoantimonate complex, 4,4′-bipyridinium(2+) di-μ-iodo-bis[(4,4′-bipyridyl)triiodoantimony(III)], formulated as [4,4′-H2bipy]2+[Sb2I8(4,4′-bipy)2]2− or (C10H10N2)[Sb2I8(C10H8N2)2], contains layers of hydrogen-bonded ribbon polymers in which anionic dimetal complexes are linked through hydrogen bonding with 4,4′-H2bipy cations. The complex is isostructural with its bismuth analogue.

U2 - 10.1107/S1600536803022347

DO - 10.1107/S1600536803022347

M3 - Article (Academic Journal)

SN - 1600-5368

VL - 59

SP - m997-m999

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

4,4'-bipyridyl adduct of an iodoantimonate anion linked by a 4,4'-bipypridium cation

Abstract

Bibliographical note

Access to Document

Handle.net

Fingerprint

Cite this