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A comparison of two high spatial resolution imaging techniques for determining carbide precipitate type and size in ferritic 9Cr-1Mo steel

Research output: Contribution to journalArticle

Original languageEnglish
Pages (from-to)13-19
Number of pages7
JournalUltramicroscopy
Volume205
Early online date10 Jun 2019
DOIs
DateAccepted/In press - 9 Jun 2019
DateE-pub ahead of print - 10 Jun 2019
DatePublished (current) - 1 Oct 2019

Abstract

Two high spatial resolution imaging techniques, focused gallium ion beam imaging in conjunction with XeF2 gas (FIB/XeF2) and high-speed atomic force microscopy (HS-AFM), were used to analyse 9Cr-1Mo ferritic steel samples, which had been exposed for extended periods to hot CO2 gas containing traces of CO, H2, H2O and CH4. The carbide precipitates embedded in the metal matrix were observed and their morphology, size and spatial distribution were quantified using these two techniques. The lower resolution of the FIB/XeF2 imaging technique suggested that small carbide precipitates (<50 nm) may be missed, while the existence of a limited flow layer introduced by sample preparation may influence the HS-AFM results. The gallium ion beam was used to remove a thin oxide layer of approximately 50 nm from sample surfaces prior to FIB/XeF2 imaging, avoiding the influence of surface contamination. HS-AFM provided higher resolution (~5 nm) than FIB/XeF2 imaging. A quantitative comparison of the experimental data confirmed the value of both FIB/XeF2 and HS-AFM for imaging carbide precipitates, while clarifying their strengths and limitations.

    Research areas

  • 9Cr-1Mo steel, FIB imaging with XeF2, High-speed atomic force microscopy, carbide area fraction

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  • Full-text PDF (accepted author manuscript)

    Rights statement: This is the accepted author manuscript (AAM). The final published version (version of record) is available online via Elsevier at https://doi.org/10.1016/j.ultramic.2019.06.005 . Please refer to any applicable terms of use of the publisher.

    Accepted author manuscript, 828 KB, PDF document

    Embargo ends: 10/06/20

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    Licence: CC BY-NC-ND

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