A large source of atomic chlorine from ClNO2 photolysis at a UK landfill site

Thomas Bannan, Anwar Khan, Michael Le Breton, Michael Priestley, Stephen Worrall, Asan Bacak, Nicholas Marsden, Douglas Lowe, Joe Pitt, Grant Allen, David Topping, Hugh Coe, Gordon McFiggans, Dudley Shallcross, Carl Percival

Research output: Contribution to journalArticle (Academic Journal)peer-review

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Nitryl Chloride (ClNO2) acts as a source of highly reactive chlorine atoms as well as an important NOx reservoir. Measurements of ClNO2 at an operational UK landfill site are reported here for the first time. A peak concentration of 4 ppb of ClNO2 was found with a peak mean night time maximum of 0.9 ppb. Using models based upon the photolysis of observed ClNO2 and atmospheric chlorine chemistry, chlorine atom concentrations reaching in excess of 1.20 x 105 molecules cm-3 in the early morning following sunrise are calculated. These concentrations are approximately 10 times higher than previously reported in the UK, suggesting a significant impact on the oxidising capacity around such sites. Given the ubiquity of landfill sites regionally and globally, and the large abundances of Cl atoms from the photolysis of ClNO2, chlorine chemistry has a significant impact on ozone formation and VOCs oxidation as shown by WRF-Chem modelling.
Original languageEnglish
Pages (from-to)8508-8516
Number of pages9
JournalGeophysical Research Letters
Publication statusPublished - 29 Jul 2019


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