A new family of metallaboratrane complexes based on 7-azaindole: B-H activation mediated by carbon monoxide

Nikolaos Tsoureas; Mairi F. Haddow; Alex Hamilton; Gareth R. Owen

doi:10.1039/b822678d

A new family of metallaboratrane complexes based on 7-azaindole: B-H activation mediated by carbon monoxide

Nikolaos Tsoureas, Mairi F. Haddow, Alex Hamilton, Gareth R. Owen

School of Chemistry

Research output: Contribution to journal › Review article (Academic Journal) › peer-review

58 Citations (Scopus)

Abstract

The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl)(3)}(-)] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.

Original language	English
Pages (from-to)	2538-2540
Number of pages	3
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/b822678d
Publication status	Published - Mar 2009

Bibliographical note

Author of Publication Reviewed: Nikolaos Tsoureas, Mairi F. Haddow, Alex Hamilton and Gareth R. Owen

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A 500MHZ NMR SPECTROMETER TO UNDERPIN CHEMICAL RESEARCH AT BRISTOL
Simpson, T. J. (Principal Investigator)
1/09/07 → 1/09/10
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Cite this

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title = "A new family of metallaboratrane complexes based on 7-azaindole: B-H activation mediated by carbon monoxide",

abstract = "The reaction of Ir(COD)(Tai) [where Tai = \{HB(7-azaindoyl)(3)\}(-)] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.",

author = "Nikolaos Tsoureas and Haddow, \{Mairi F.\} and Alex Hamilton and Owen, \{Gareth R.\}",

note = "Author of Publication Reviewed: Nikolaos Tsoureas, Mairi F. Haddow, Alex Hamilton and Gareth R. Owen",

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doi = "10.1039/b822678d",

language = "English",

pages = "2538--2540",

journal = "Chemical Communications",

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AU - Tsoureas, Nikolaos

AU - Haddow, Mairi F.

AU - Hamilton, Alex

AU - Owen, Gareth R.

N1 - Author of Publication Reviewed: Nikolaos Tsoureas, Mairi F. Haddow, Alex Hamilton and Gareth R. Owen

PY - 2009/3

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N2 - The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl)(3)}(-)] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.

AB - The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl)(3)}(-)] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.

U2 - 10.1039/b822678d

DO - 10.1039/b822678d

M3 - Review article (Academic Journal)

C2 - 19532882

SN - 1359-7345

SP - 2538

EP - 2540

JO - Chemical Communications

JF - Chemical Communications

IS - 18

ER -

A new family of metallaboratrane complexes based on 7-azaindole: B-H activation mediated by carbon monoxide

Abstract

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A 500MHZ NMR SPECTROMETER TO UNDERPIN CHEMICAL RESEARCH AT BRISTOL

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