A Self-Assembling Flavin for Visible Photooxidation

Michele Cariello; Bart Dietrich; Lisa Thomson; Valentina Gauci; Alistair Boyer; Stephen Sproules; Graeme Cooke; Annela Seddon; Dave J. Adams

doi:10.1002/chem.202201725

A Self-Assembling Flavin for Visible Photooxidation

Michele Cariello, Bart Dietrich, Lisa Thomson, Valentina Gauci, Alistair Boyer, Stephen Sproules, Graeme Cooke, Annela Seddon, Dave J. Adams^*

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

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Abstract

A new flavin-based gelator is reported which forms micellar structures at high pH and gels at low pH. This flavin can be used for the photooxidation of thiols under visible light, with the catalytic efficiency being linked to the self-assembled structures present.

Original language	English
Article number	e202201725
Journal	Chemistry - A European Journal
Volume	28
Issue number	49
Early online date	22 Jul 2022
DOIs	https://doi.org/10.1002/chem.202201725
Publication status	E-pub ahead of print - 22 Jul 2022

Bibliographical note

Funding Information:
BD and DA thank the EPSRC for funding (EP/L021978/2). GC thanks the EPSRC for funding (EP/E036244/1). AB thanks the Royal Society and TATA for a University Research Fellowship. This work benefitted from the SasView software, originally developed by the DANSE project under NSF award DMR‐0520547. The Ganesha X‐ray scattering apparatus was purchased under EPSRC Grant ‘Atoms to Applications’ (EP/K035746/1).

Publisher Copyright:
© 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.

Keywords

catalysis
flavin
gel
oxidation
supramolecular

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title = "A Self-Assembling Flavin for Visible Photooxidation",

abstract = "A new flavin-based gelator is reported which forms micellar structures at high pH and gels at low pH. This flavin can be used for the photooxidation of thiols under visible light, with the catalytic efficiency being linked to the self-assembled structures present.",

keywords = "catalysis, flavin, gel, oxidation, supramolecular",

author = "Michele Cariello and Bart Dietrich and Lisa Thomson and Valentina Gauci and Alistair Boyer and Stephen Sproules and Graeme Cooke and Annela Seddon and Adams, {Dave J.}",

note = "Funding Information: BD and DA thank the EPSRC for funding (EP/L021978/2). GC thanks the EPSRC for funding (EP/E036244/1). AB thanks the Royal Society and TATA for a University Research Fellowship. This work benefitted from the SasView software, originally developed by the DANSE project under NSF award DMR‐0520547. The Ganesha X‐ray scattering apparatus was purchased under EPSRC Grant {\textquoteleft}Atoms to Applications{\textquoteright} (EP/K035746/1). Publisher Copyright: {\textcopyright} 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.",

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AU - Cariello, Michele

AU - Dietrich, Bart

AU - Thomson, Lisa

AU - Gauci, Valentina

AU - Boyer, Alistair

AU - Sproules, Stephen

AU - Cooke, Graeme

AU - Seddon, Annela

AU - Adams, Dave J.

N1 - Funding Information: BD and DA thank the EPSRC for funding (EP/L021978/2). GC thanks the EPSRC for funding (EP/E036244/1). AB thanks the Royal Society and TATA for a University Research Fellowship. This work benefitted from the SasView software, originally developed by the DANSE project under NSF award DMR‐0520547. The Ganesha X‐ray scattering apparatus was purchased under EPSRC Grant ‘Atoms to Applications’ (EP/K035746/1). Publisher Copyright: © 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.

PY - 2022/7/22

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N2 - A new flavin-based gelator is reported which forms micellar structures at high pH and gels at low pH. This flavin can be used for the photooxidation of thiols under visible light, with the catalytic efficiency being linked to the self-assembled structures present.

AB - A new flavin-based gelator is reported which forms micellar structures at high pH and gels at low pH. This flavin can be used for the photooxidation of thiols under visible light, with the catalytic efficiency being linked to the self-assembled structures present.

KW - catalysis

KW - flavin

KW - gel

KW - oxidation

KW - supramolecular

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M3 - Article (Academic Journal)

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JF - Chemistry - A European Journal

IS - 49

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ER -

A Self-Assembling Flavin for Visible Photooxidation

Abstract

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Keywords

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