A Simple Ag(I)-Enyne Cation

Rajashekharayya Sanguramath; Nell Townsend; Chris Russell

doi:10.1016/j.jorganchem.2016.03.009

A Simple Ag(I)-Enyne Cation

Rajashekharayya Sanguramath, Nell Townsend, Chris Russell

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Abstract

A simple cationic Ag(I)-1,3-enyne complex was synthesized and characterized. In the solid state, single crystal X-ray crystallography showed the Ag(I) centre bonded in an asymmetric manner exclusively to the alkyne portion of the substrate. NMR spectroscopy studies showed this structure is maintained in solution over the temperature range of -90 to +60 °C.

Original language	English
Pages (from-to)	26–28
Number of pages	3
Journal	Journal of Organometallic Chemistry
Volume	811
Early online date	10 Mar 2016
DOIs	https://doi.org/10.1016/j.jorganchem.2016.03.009
Publication status	Published - 1 Jun 2016

Structured keywords

BCS and TECS CDTs

Keywords

Silver
1,3-enyne
X-ray crystallography
Cation

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10.1016/j.jorganchem.2016.03.009

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This is the author accepted manuscript (AAM). The final published version (version of record) is available online via Elsevier at http://www.sciencedirect.com/science/article/pii/S0022328X16300821. Please refer to any applicable terms of use of the publisher.
Accepted author manuscript, 309 KBLicence: CC BY-NC-ND

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3-month Core Capability for Chemistry Research
Crosby, J.
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Dr Chris A Russell
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Cite this

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title = "A Simple Ag(I)-Enyne Cation",

abstract = "A simple cationic Ag(I)-1,3-enyne complex was synthesized and characterized. In the solid state, single crystal X-ray crystallography showed the Ag(I) centre bonded in an asymmetric manner exclusively to the alkyne portion of the substrate. NMR spectroscopy studies showed this structure is maintained in solution over the temperature range of -90 to +60 °C.",

keywords = "Silver, 1,3-enyne, X-ray crystallography, Cation",

author = "Rajashekharayya Sanguramath and Nell Townsend and Chris Russell",

year = "2016",

month = jun,

day = "1",

doi = "10.1016/j.jorganchem.2016.03.009",

language = "English",

volume = "811",

pages = "26–28",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

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TY - JOUR

T1 - A Simple Ag(I)-Enyne Cation

AU - Sanguramath, Rajashekharayya

AU - Townsend, Nell

AU - Russell, Chris

PY - 2016/6/1

Y1 - 2016/6/1

N2 - A simple cationic Ag(I)-1,3-enyne complex was synthesized and characterized. In the solid state, single crystal X-ray crystallography showed the Ag(I) centre bonded in an asymmetric manner exclusively to the alkyne portion of the substrate. NMR spectroscopy studies showed this structure is maintained in solution over the temperature range of -90 to +60 °C.

AB - A simple cationic Ag(I)-1,3-enyne complex was synthesized and characterized. In the solid state, single crystal X-ray crystallography showed the Ag(I) centre bonded in an asymmetric manner exclusively to the alkyne portion of the substrate. NMR spectroscopy studies showed this structure is maintained in solution over the temperature range of -90 to +60 °C.

KW - Silver

KW - 1,3-enyne

KW - X-ray crystallography

KW - Cation

U2 - 10.1016/j.jorganchem.2016.03.009

DO - 10.1016/j.jorganchem.2016.03.009

M3 - Article (Academic Journal)

VL - 811

SP - 26

EP - 28

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

ER -

A Simple Ag(I)-Enyne Cation

Abstract

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Keywords

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Dr Chris A Russell

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