A Simple Ag(I)-Enyne Cation

Rajashekharayya Sanguramath, Nell Townsend, Chris Russell

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Abstract

A simple cationic Ag(I)-1,3-enyne complex was synthesized and characterized. In the solid state, single crystal X-ray crystallography showed the Ag(I) centre bonded in an asymmetric manner exclusively to the alkyne portion of the substrate. NMR spectroscopy studies showed this structure is maintained in solution over the temperature range of -90 to +60 °C.
Original languageEnglish
Pages (from-to)26–28
Number of pages3
JournalJournal of Organometallic Chemistry
Volume811
Early online date10 Mar 2016
DOIs
Publication statusPublished - 1 Jun 2016

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Structured keywords

  • BCS and TECS CDTs

Keywords

  • Silver
  • 1,3-enyne
  • X-ray crystallography
  • Cation

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