A simple approach to room temperature phosphorescent allenylidene complexes

Florian Kessler; Basile F E Curchod; Ivano Tavernelli; Ursula Rothlisberger; Rosario Scopelliti; Davide Di Censo; Michael Grätzel; Md Khaja Nazeeruddin; Etienne Baranoff

doi:10.1002/anie.201203329

A simple approach to room temperature phosphorescent allenylidene complexes

Florian Kessler
, Basile F E Curchod
, Ivano Tavernelli
, Ursula Rothlisberger
, Rosario Scopelliti
, Davide Di Censo
, Michael Grätzel
, Md Khaja Nazeeruddin^*
, Etienne Baranoff

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

23 Citations (Scopus)

Abstract

A warm (blue) glow: A stable bis-cyclometalated iridium(III) allenylidene complex is prepared from a bis-cyclometalated iridium(III) complex (see scheme). This strategy gives the first allenylidene complex that is phosphorescent at room temperature.

Original language	English
Pages (from-to)	8030-8033
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	32
DOIs	https://doi.org/10.1002/anie.201203329
Publication status	Published - 6 Aug 2012

Research Groups and Themes

Physical & Theoretical

Keywords

alkynyl complexes
allenylidene complexes
carbenes
cumulenes
phosphorescent iridium complexes

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10.1002/anie.201203329

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title = "A simple approach to room temperature phosphorescent allenylidene complexes",

abstract = "A warm (blue) glow: A stable bis-cyclometalated iridium(III) allenylidene complex is prepared from a bis-cyclometalated iridium(III) complex (see scheme). This strategy gives the first allenylidene complex that is phosphorescent at room temperature.",

keywords = "alkynyl complexes, allenylidene complexes, carbenes, cumulenes, phosphorescent iridium complexes",

author = "Florian Kessler and Curchod, \{Basile F E\} and Ivano Tavernelli and Ursula Rothlisberger and Rosario Scopelliti and \{Di Censo\}, Davide and Michael Gr{\"a}tzel and Nazeeruddin, \{Md Khaja\} and Etienne Baranoff",

year = "2012",

month = aug,

day = "6",

doi = "10.1002/anie.201203329",

language = "English",

volume = "51",

pages = "8030--8033",

journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - A simple approach to room temperature phosphorescent allenylidene complexes

AU - Kessler, Florian

AU - Curchod, Basile F E

AU - Tavernelli, Ivano

AU - Rothlisberger, Ursula

AU - Scopelliti, Rosario

AU - Di Censo, Davide

AU - Grätzel, Michael

AU - Nazeeruddin, Md Khaja

AU - Baranoff, Etienne

PY - 2012/8/6

Y1 - 2012/8/6

N2 - A warm (blue) glow: A stable bis-cyclometalated iridium(III) allenylidene complex is prepared from a bis-cyclometalated iridium(III) complex (see scheme). This strategy gives the first allenylidene complex that is phosphorescent at room temperature.

AB - A warm (blue) glow: A stable bis-cyclometalated iridium(III) allenylidene complex is prepared from a bis-cyclometalated iridium(III) complex (see scheme). This strategy gives the first allenylidene complex that is phosphorescent at room temperature.

KW - alkynyl complexes

KW - allenylidene complexes

KW - carbenes

KW - cumulenes

KW - phosphorescent iridium complexes

UR - https://www.scopus.com/pages/publications/84864742976

U2 - 10.1002/anie.201203329

DO - 10.1002/anie.201203329

M3 - Article (Academic Journal)

C2 - 22753404

AN - SCOPUS:84864742976

SN - 1433-7851

VL - 51

SP - 8030

EP - 8033

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 32

ER -

A simple approach to room temperature phosphorescent allenylidene complexes

Abstract

Research Groups and Themes

Keywords

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