A simple route to azaborinylphosphines: Isoelectronic B-N analogues of arylphosphine ligands

Jonathan A. Bailey; Mairi F. Haddow; Paul G. Pringle

doi:10.1039/c3cc49000a

A simple route to azaborinylphosphines: Isoelectronic B-N analogues of arylphosphine ligands

Jonathan A. Bailey, Mairi F. Haddow, Paul G. Pringle^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

29 Citations (Scopus)

Abstract

Azaborinylphosphines are readily prepared by the reaction of silylphosphines with a chloroborane under mild conditions; they are shown to contain P-B bonds that are sufficiently robust to allow these ligands to be used in homogeneous catalysis. This journal is © The Royal Society of Chemistry.

Original language	English
Pages (from-to)	1432-1434
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	12
DOIs	https://doi.org/10.1039/c3cc49000a
Publication status	Published - 11 Feb 2014

Keywords

PHOSPHINOBORANES R2PB(C6F5)(2)
CATALYSIS

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title = "A simple route to azaborinylphosphines: Isoelectronic B-N analogues of arylphosphine ligands",

abstract = "Azaborinylphosphines are readily prepared by the reaction of silylphosphines with a chloroborane under mild conditions; they are shown to contain P-B bonds that are sufficiently robust to allow these ligands to be used in homogeneous catalysis. This journal is {\textcopyright} The Royal Society of Chemistry.",

keywords = "PHOSPHINOBORANES R2PB(C6F5)(2), CATALYSIS",

author = "Bailey, {Jonathan A.} and Haddow, {Mairi F.} and Pringle, {Paul G.}",

year = "2014",

month = feb,

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doi = "10.1039/c3cc49000a",

language = "English",

volume = "50",

pages = "1432--1434",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - A simple route to azaborinylphosphines

T2 - Isoelectronic B-N analogues of arylphosphine ligands

AU - Bailey, Jonathan A.

AU - Haddow, Mairi F.

AU - Pringle, Paul G.

PY - 2014/2/11

Y1 - 2014/2/11

N2 - Azaborinylphosphines are readily prepared by the reaction of silylphosphines with a chloroborane under mild conditions; they are shown to contain P-B bonds that are sufficiently robust to allow these ligands to be used in homogeneous catalysis. This journal is © The Royal Society of Chemistry.

AB - Azaborinylphosphines are readily prepared by the reaction of silylphosphines with a chloroborane under mild conditions; they are shown to contain P-B bonds that are sufficiently robust to allow these ligands to be used in homogeneous catalysis. This journal is © The Royal Society of Chemistry.

KW - PHOSPHINOBORANES R2PB(C6F5)(2)

KW - CATALYSIS

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U2 - 10.1039/c3cc49000a

DO - 10.1039/c3cc49000a

M3 - Article (Academic Journal)

C2 - 24345849

SN - 1359-7345

VL - 50

SP - 1432

EP - 1434

JO - Chemical Communications

JF - Chemical Communications

IS - 12

ER -

A simple route to azaborinylphosphines: Isoelectronic B-N analogues of arylphosphine ligands

Abstract

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A simple route to azaborinylphosphines: Isoelectronic B-N analogues of arylphosphine ligands

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