An estimate of the global budget and distribution of ethanol using a global 3-D atmospheric chemistry transport model STOCHEM-CRI

Anwar Khan, H. Glaubes, A Kent, Tim Harrison, Amy Foulds, Carl J. Percival, Dudley Shallcross

Research output: Contribution to journalArticle (Academic Journal)peer-review

4 Citations (Scopus)
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Abstract

The atmospheric global budget and distribution of ethanol have been investigated using a global 3-dimensional chemistry transport model, STOCHEM-CRI. Ethanol, a precursor to acetaldehyde and peroxyacetyl nitrate (PAN), is found throughout the troposphere with a global burden of 0.024–0.25 Tg. The atmospheric lifetime of ethanol is found to be 1.1–2.8 days, which is in excellent agreement with estimates established by previous studies. The main global source of ethanol is from direct emission (99%) and the remainder (1%) being produced via peroxy radical reactions. In terms of removal rates of ethanol in the atmosphere, oxidation by hydroxyl radicals (OH) accounted for 51%, dry deposition 8% and wet deposition accounted for 41%. Globally there are significant concentrations of ethanol over equatorial Africa, North America and parts of Asia with considerably higher concentrations modelled over Saudi Arabia and Eastern Canada. Through comparison of measured and modelled ethanol data, it is apparent that the underestimation of the source strength of ethanol and the coarse resolution of the STOCHEM-CRI model produce the discrepancies between the model and the measured data mostly in urban areas. The increased vegetation and anthropogenic emissions of ethanol lead to an increase in the production of acetaldehyde (by up to 90%) and peroxyacetyl nitrate (by up to 10%) which disrupts the NOx-ozone balance, promoting ozone production (by up to 1.4%) in the equatorial regions.
Original languageEnglish
Pages (from-to)174-183
Number of pages11
JournalTransactions of the Royal Society of South Africa
Volume72
Issue number2
Early online date7 Feb 2017
DOIs
Publication statusPublished - May 2017

Keywords

  • global burden
  • atmospheric lifetime
  • chemistry transport model
  • equatorial region
  • urban areas

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