Anionic Surfactant Ionic Liquids with 1-Butyl-3-methyl-imidazolium Cations: Characterization and Application

Paul Brown; Craig P. Butts; Julian Eastoe; David Fermin; Isabelle Grillo; Huai-Chin Lee; David Parker; Daniela Plana; Robert M. Richardson

doi:10.1021/la204557t

Anionic Surfactant Ionic Liquids with 1-Butyl-3-methyl-imidazolium Cations: Characterization and Application

Paul Brown, Craig P. Butts, Julian Eastoe, David Fermin, Isabelle Grillo, Huai-Chin Lee, David Parker, Daniela Plana, Robert M. Richardson

Research output: Contribution to journal › Article (Academic Journal) › peer-review

190 Citations (Scopus)

Abstract

For the first time a series of anionic surfactant ionic liquids (SAILs) has been synthesized based on organic surfactant anions and 1-butyl-3-methyl-imidazolium cations. These compounds are more environmentally friendly and chemically tunable as compared to other common ionic liquids. A detailed investigation of physicochemical properties highlights potential applications from battery design to reaction control, and studies into aqueous aggregation behavior, as well as structuring in pure ILs, point to possible uses in electrochemistry.

Original language	English
Pages (from-to)	2502-2509
Number of pages	8
Journal	Langmuir
Volume	28
Issue number	5
DOIs	https://doi.org/10.1021/la204557t
Publication status	Published - 7 Feb 2012

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abstract = "For the first time a series of anionic surfactant ionic liquids (SAILs) has been synthesized based on organic surfactant anions and 1-butyl-3-methyl-imidazolium cations. These compounds are more environmentally friendly and chemically tunable as compared to other common ionic liquids. A detailed investigation of physicochemical properties highlights potential applications from battery design to reaction control, and studies into aqueous aggregation behavior, as well as structuring in pure ILs, point to possible uses in electrochemistry.",

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AU - Eastoe, Julian

AU - Fermin, David

AU - Grillo, Isabelle

AU - Lee, Huai-Chin

AU - Parker, David

AU - Plana, Daniela

AU - Richardson, Robert M.

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AB - For the first time a series of anionic surfactant ionic liquids (SAILs) has been synthesized based on organic surfactant anions and 1-butyl-3-methyl-imidazolium cations. These compounds are more environmentally friendly and chemically tunable as compared to other common ionic liquids. A detailed investigation of physicochemical properties highlights potential applications from battery design to reaction control, and studies into aqueous aggregation behavior, as well as structuring in pure ILs, point to possible uses in electrochemistry.

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Anionic Surfactant Ionic Liquids with 1-Butyl-3-methyl-imidazolium Cations: Characterization and Application

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