Application of pulsed electrolysis in organic electrosynthesis

The field of organic electrochemistry has regained significant interest over recent years. The unique level of control afforded to the user over reaction kinetics and selectivity is a driving force behind this. The use of non-standard electrolysis waveforms, such as alternating polarity electrolysis, has been shown to offer a degree of variation and control that facilitates new opportunities in the field. The generation of pulsed electrolysis waveforms via the introduction of a resting period during electrolysis is underexplored in organic electrosynthesis. Recent case studies demonstrate that this is a potentially powerful technique that can aid the control of dynamic redox environments for greater reaction success.