Application of the Lithiation-Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry

M Althaus; A Mahmood; JR Suarez; SP Thomas; VK Aggarwal

doi:10.1021/ja910593w

Application of the Lithiation-Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry

M Althaus, A Mahmood, JR Suarez, SP Thomas, VK Aggarwal

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

126 Citations (Scopus)

Translated title of the contribution	Application of the Lithiation-Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry
Original language	English
Pages (from-to)	4025 - 4028
Journal	Journal of the American Chemical Society
Volume	132
DOIs	https://doi.org/10.1021/ja910593w
Publication status	Published - 2010

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Organic & Biological

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NEW ASSYMETRIC REACTIONS AND THEIR APPLICATION IN TOTAL SYNTHESIS
Aggarwal, V. K. (Principal Investigator)
1/10/05 → 1/10/10
Project: Research

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Althaus, M., Mahmood, A., Suarez, JR., Thomas, SP., & Aggarwal, VK. (2010). Application of the Lithiation-Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry. Journal of the American Chemical Society, 132, 4025 - 4028. https://doi.org/10.1021/ja910593w

Althaus, M ; Mahmood, A ; Suarez, JR et al. / Application of the Lithiation-Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry. In: Journal of the American Chemical Society. 2010 ; Vol. 132. pp. 4025 - 4028.

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title = "Application of the Lithiation-Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry",

author = "M Althaus and A Mahmood and JR Suarez and SP Thomas and VK Aggarwal",

year = "2010",

doi = "10.1021/ja910593w",

language = "English",

volume = "132",

pages = "4025 -- 4028",

journal = "Journal of the American Chemical Society",

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Althaus, M, Mahmood, A, Suarez, JR, Thomas, SP & Aggarwal, VK 2010, 'Application of the Lithiation-Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry', Journal of the American Chemical Society, vol. 132, pp. 4025 - 4028. https://doi.org/10.1021/ja910593w

Application of the Lithiation-Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry. / Althaus, M; Mahmood, A; Suarez, JR et al.
In: Journal of the American Chemical Society, Vol. 132, 2010, p. 4025 - 4028.

Research output: Contribution to journal › Article (Academic Journal) › peer-review

TY - JOUR

T1 - Application of the Lithiation-Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry

AU - Althaus, M

AU - Mahmood, A

AU - Suarez, JR

AU - Thomas, SP

AU - Aggarwal, VK

PY - 2010

Y1 - 2010

U2 - 10.1021/ja910593w

DO - 10.1021/ja910593w

M3 - Article (Academic Journal)

C2 - 20192266

SN - 1520-5126

VL - 132

SP - 4025

EP - 4028

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

ER -

Althaus M, Mahmood A, Suarez JR, Thomas SP, Aggarwal VK. Application of the Lithiation-Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry. Journal of the American Chemical Society. 2010;132:4025 - 4028. doi: 10.1021/ja910593w

Application of the Lithiation-Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry

Research Groups and Themes

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NEW ASSYMETRIC REACTIONS AND THEIR APPLICATION IN TOTAL SYNTHESIS

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