Aqueous recognition of purine and pyrimidine bases by an anthracene-based macrocyclic receptor

Danny Van Eker; Soumen K. Samanta; Anthony P. Davis

doi:10.1039/D0CC03609A

Aqueous recognition of purine and pyrimidine bases by an anthracene-based macrocyclic receptor

Danny Van Eker, Soumen K. Samanta, Anthony P. Davis

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Abstract

A water-soluble bis-anthracenyl tetralactam binds biogenic heterocycles with high affinities in aqueous solution, rising to 107 M−1 for the purine hypoxanthine. Recognition occurs through a combination of hydrogen bonding and hydrophobic interactions, and results in fluorescence changes which suggest applications in sensing.

Original language	English
Pages (from-to)	9268-9271
Number of pages	4
Journal	Chemical Communications
Issue number	65
DOIs	https://doi.org/10.1039/D0CC03609A
Publication status	Published - 24 Jun 2020

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10.1039/D0CC03609A

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This is the author accepted manuscript (AAM). The final published version (version of record) is available online via Royal Society of Chemistry at https://pubs.rsc.org/en/content/articlelanding/2020/cc/d0cc03609a#!divAbstract . Please refer to any applicable terms of use of the publisher.
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title = "Aqueous recognition of purine and pyrimidine bases by an anthracene-based macrocyclic receptor",

abstract = "A water-soluble bis-anthracenyl tetralactam binds biogenic heterocycles with high affinities in aqueous solution, rising to 107 M−1 for the purine hypoxanthine. Recognition occurs through a combination of hydrogen bonding and hydrophobic interactions, and results in fluorescence changes which suggest applications in sensing.",

author = "Eker, {Danny Van} and Samanta, {Soumen K.} and Davis, {Anthony P.}",

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N2 - A water-soluble bis-anthracenyl tetralactam binds biogenic heterocycles with high affinities in aqueous solution, rising to 107 M−1 for the purine hypoxanthine. Recognition occurs through a combination of hydrogen bonding and hydrophobic interactions, and results in fluorescence changes which suggest applications in sensing.

AB - A water-soluble bis-anthracenyl tetralactam binds biogenic heterocycles with high affinities in aqueous solution, rising to 107 M−1 for the purine hypoxanthine. Recognition occurs through a combination of hydrogen bonding and hydrophobic interactions, and results in fluorescence changes which suggest applications in sensing.

U2 - 10.1039/D0CC03609A

DO - 10.1039/D0CC03609A

M3 - Article (Academic Journal)

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JO - Chemical Communications

JF - Chemical Communications

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Aqueous recognition of purine and pyrimidine bases by an anthracene-based macrocyclic receptor

Abstract

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