Asymmetric Synthesis of Allylsilanes by the Borylation of Lithiated Carbamates: Formal Total Synthesis of (-)-Decarestrictine D

Michael Binanzer; Guang Yu Fang; Varinder K. Aggarwal

doi:10.1002/anie.201001223

Asymmetric Synthesis of Allylsilanes by the Borylation of Lithiated Carbamates: Formal Total Synthesis of (-)-Decarestrictine D

Michael Binanzer
, Guang Yu Fang
, Varinder K. Aggarwal^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

78 Citations (Scopus)

Original language	English
Pages (from-to)	4264-4268
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	25
DOIs	https://doi.org/10.1002/anie.201001223
Publication status	Published - 2010

Research Groups and Themes

Organic & Biological

Keywords

boranes
borates
homologation
lithium
natural products
ENANTIOSELECTIVE SYNTHESIS
ORGANIC-SYNTHESIS
DIASTEREOSELECTIVE SYNTHESIS
ALPHA-HYDROXYALLYLATION
SECONDARY ALCOHOLS
MALIC-ACID
REAGENTS
ALDEHYDES
STEREOCHEMISTRY
2-BUTENE-1,4-DIOLS

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10.1002/anie.201001223

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Persistent link

NEW ASSYMETRIC REACTIONS AND THEIR APPLICATION IN TOTAL SYNTHESIS
Aggarwal, V. K. (Principal Investigator)
1/10/05 → 1/10/10
Project: Research

Cite this

@article{7cfaa53c6a624bfd8986a5681b46f596,

title = "Asymmetric Synthesis of Allylsilanes by the Borylation of Lithiated Carbamates: Formal Total Synthesis of (-)-Decarestrictine D",

keywords = "boranes, borates, homologation, lithium, natural products, ENANTIOSELECTIVE SYNTHESIS, ORGANIC-SYNTHESIS, DIASTEREOSELECTIVE SYNTHESIS, ALPHA-HYDROXYALLYLATION, SECONDARY ALCOHOLS, MALIC-ACID, REAGENTS, ALDEHYDES, STEREOCHEMISTRY, 2-BUTENE-1,4-DIOLS",

author = "Michael Binanzer and Fang, \{Guang Yu\} and Aggarwal, \{Varinder K.\}",

year = "2010",

doi = "10.1002/anie.201001223",

language = "English",

volume = "49",

pages = "4264--4268",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley \& Sons, Ltd.",

number = "25",

}

TY - JOUR

T1 - Asymmetric Synthesis of Allylsilanes by the Borylation of Lithiated Carbamates

T2 - Formal Total Synthesis of (-)-Decarestrictine D

AU - Binanzer, Michael

AU - Fang, Guang Yu

AU - Aggarwal, Varinder K.

PY - 2010

Y1 - 2010

KW - boranes

KW - borates

KW - homologation

KW - lithium

KW - natural products

KW - ENANTIOSELECTIVE SYNTHESIS

KW - ORGANIC-SYNTHESIS

KW - DIASTEREOSELECTIVE SYNTHESIS

KW - ALPHA-HYDROXYALLYLATION

KW - SECONDARY ALCOHOLS

KW - MALIC-ACID

KW - REAGENTS

KW - ALDEHYDES

KW - STEREOCHEMISTRY

KW - 2-BUTENE-1,4-DIOLS

U2 - 10.1002/anie.201001223

DO - 10.1002/anie.201001223

M3 - Article (Academic Journal)

C2 - 20446329

SN - 1433-7851

VL - 49

SP - 4264

EP - 4268

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 25

ER -

Asymmetric Synthesis of Allylsilanes by the Borylation of Lithiated Carbamates: Formal Total Synthesis of (-)-Decarestrictine D

Research Groups and Themes

Keywords

Access to Document

Handle.net

Projects

NEW ASSYMETRIC REACTIONS AND THEIR APPLICATION IN TOTAL SYNTHESIS

Cite this