Asymmetric Total Synthesis of Solandelactone E: Stereocontrolled Synthesis of the 2-ene-1,4-diol Core through a Lithiation-Borylation-Allylation Sequence

Anna Robinson; Varinder K. Aggarwal

doi:10.1002/anie.201003236

Asymmetric Total Synthesis of Solandelactone E: Stereocontrolled Synthesis of the 2-ene-1,4-diol Core through a Lithiation-Borylation-Allylation Sequence

Anna Robinson, Varinder K. Aggarwal^*

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

43 Citations (Scopus)

Original language	English
Pages (from-to)	6673-6675
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	37
DOIs	https://doi.org/10.1002/anie.201003236
Publication status	Published - 2010

Keywords

allyl silanes
1,4-ene-diols
lithiation-borylation
natural products
total synthesis
HYDROID SOLANDERIA-SECUNDA
ALGA CONSTANTINEA-SIMPLEX
ENANTIOSELECTIVE SYNTHESIS
STRUCTURE REVISION
CONSTANOLACTONE-B
CYCLOPROPANATION
HALICHOLACTONE
OXYLIPINS
REAGENTS
NEOHALICHOLACTONE

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10.1002/anie.201003236

Cite this

@article{e349ce848a954b6c99695fa28db231b0,

title = "Asymmetric Total Synthesis of Solandelactone E: Stereocontrolled Synthesis of the 2-ene-1,4-diol Core through a Lithiation-Borylation-Allylation Sequence",

keywords = "allyl silanes, 1,4-ene-diols, lithiation-borylation, natural products, total synthesis, HYDROID SOLANDERIA-SECUNDA, ALGA CONSTANTINEA-SIMPLEX, ENANTIOSELECTIVE SYNTHESIS, STRUCTURE REVISION, CONSTANOLACTONE-B, CYCLOPROPANATION, HALICHOLACTONE, OXYLIPINS, REAGENTS, NEOHALICHOLACTONE",

author = "Anna Robinson and Aggarwal, {Varinder K.}",

year = "2010",

doi = "10.1002/anie.201003236",

language = "English",

volume = "49",

pages = "6673--6675",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "Wiley-VCH Verlag",

number = "37",

}

TY - JOUR

T1 - Asymmetric Total Synthesis of Solandelactone E

T2 - Stereocontrolled Synthesis of the 2-ene-1,4-diol Core through a Lithiation-Borylation-Allylation Sequence

AU - Robinson, Anna

AU - Aggarwal, Varinder K.

PY - 2010

Y1 - 2010

KW - allyl silanes

KW - 1,4-ene-diols

KW - lithiation-borylation

KW - natural products

KW - total synthesis

KW - HYDROID SOLANDERIA-SECUNDA

KW - ALGA CONSTANTINEA-SIMPLEX

KW - ENANTIOSELECTIVE SYNTHESIS

KW - STRUCTURE REVISION

KW - CONSTANOLACTONE-B

KW - CYCLOPROPANATION

KW - HALICHOLACTONE

KW - OXYLIPINS

KW - REAGENTS

KW - NEOHALICHOLACTONE

U2 - 10.1002/anie.201003236

DO - 10.1002/anie.201003236

M3 - Article (Academic Journal)

C2 - 20683835

VL - 49

SP - 6673

EP - 6675

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 37

ER -