Benzylic Boron Reagents Behaving as Allylic Boron Reagents towards Aldehydes: A New Asymmetric Reaction Leading to Homoallylic Alcohols with Concomitant Dearomatisation

Abel Ros Lao; Antonio Bermejo; Varinder K. Aggarwal

doi:10.1002/chem.201001174

Benzylic Boron Reagents Behaving as Allylic Boron Reagents towards Aldehydes: A New Asymmetric Reaction Leading to Homoallylic Alcohols with Concomitant Dearomatisation

Abel Ros Lao, Antonio Bermejo, Varinder K. Aggarwal^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

12 Citations (Scopus)

Original language	English
Pages (from-to)	9741-9745
Number of pages	5
Journal	Chemistry - A European Journal
Volume	16
Issue number	32
DOIs	https://doi.org/10.1002/chem.201001174
Publication status	Published - 2010

Keywords

allylboration
asymmetric catalysis
borylation
dearomatization
lithiation
OXIDATIVE DEAROMATIZATION
ETA(2)-ARENE COMPLEXES
CHIRAL SECONDARY
NATURAL-PRODUCTS
ATE COMPLEXES
PENTAAMMINEOSMIUM(II)
CYCLOHEXENONES
HOMOLOGATION
CROTYLATION
DERIVATIVES

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10.1002/chem.201001174

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NEW ASSYMETRIC REACTIONS AND THEIR APPLICATION IN TOTAL SYNTHESIS
Aggarwal, V. K. (Principal Investigator)
1/10/05 → 1/10/10
Project: Research

Cite this

@article{f811a5de62364134a13f200641109134,

title = "Benzylic Boron Reagents Behaving as Allylic Boron Reagents towards Aldehydes: A New Asymmetric Reaction Leading to Homoallylic Alcohols with Concomitant Dearomatisation",

keywords = "allylboration, asymmetric catalysis, borylation, dearomatization, lithiation, OXIDATIVE DEAROMATIZATION, ETA(2)-ARENE COMPLEXES, CHIRAL SECONDARY, NATURAL-PRODUCTS, ATE COMPLEXES, PENTAAMMINEOSMIUM(II), CYCLOHEXENONES, HOMOLOGATION, CROTYLATION, DERIVATIVES",

author = "{Ros Lao}, Abel and Antonio Bermejo and Aggarwal, {Varinder K.}",

year = "2010",

doi = "10.1002/chem.201001174",

language = "English",

volume = "16",

pages = "9741--9745",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "32",

}

Benzylic Boron Reagents Behaving as Allylic Boron Reagents towards Aldehydes: A New Asymmetric Reaction Leading to Homoallylic Alcohols with Concomitant Dearomatisation. / Ros Lao, Abel; Bermejo, Antonio; Aggarwal, Varinder K.
In: Chemistry - A European Journal, Vol. 16, No. 32, 2010, p. 9741-9745.

Research output: Contribution to journal › Article (Academic Journal) › peer-review

TY - JOUR

T1 - Benzylic Boron Reagents Behaving as Allylic Boron Reagents towards Aldehydes

T2 - A New Asymmetric Reaction Leading to Homoallylic Alcohols with Concomitant Dearomatisation

AU - Ros Lao, Abel

AU - Bermejo, Antonio

AU - Aggarwal, Varinder K.

PY - 2010

Y1 - 2010

KW - allylboration

KW - asymmetric catalysis

KW - borylation

KW - dearomatization

KW - lithiation

KW - OXIDATIVE DEAROMATIZATION

KW - ETA(2)-ARENE COMPLEXES

KW - CHIRAL SECONDARY

KW - NATURAL-PRODUCTS

KW - ATE COMPLEXES

KW - PENTAAMMINEOSMIUM(II)

KW - CYCLOHEXENONES

KW - HOMOLOGATION

KW - CROTYLATION

KW - DERIVATIVES

U2 - 10.1002/chem.201001174

DO - 10.1002/chem.201001174

M3 - Article (Academic Journal)

C2 - 20589854

SN - 0947-6539

VL - 16

SP - 9741

EP - 9745

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 32

ER -

Benzylic Boron Reagents Behaving as Allylic Boron Reagents towards Aldehydes: A New Asymmetric Reaction Leading to Homoallylic Alcohols with Concomitant Dearomatisation

Keywords

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Projects

NEW ASSYMETRIC REACTIONS AND THEIR APPLICATION IN TOTAL SYNTHESIS

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