Benzylic Boron Reagents Behaving as Allylic Boron Reagents towards Aldehydes: A New Asymmetric Reaction Leading to Homoallylic Alcohols with Concomitant Dearomatisation

Abel Ros Lao; Antonio Bermejo; Varinder K. Aggarwal

doi:10.1002/chem.201001174

Benzylic Boron Reagents Behaving as Allylic Boron Reagents towards Aldehydes: A New Asymmetric Reaction Leading to Homoallylic Alcohols with Concomitant Dearomatisation

Abel Ros Lao, Antonio Bermejo, Varinder K. Aggarwal^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

12 Citations (Scopus)

Original language	English
Pages (from-to)	9741-9745
Number of pages	5
Journal	Chemistry - A European Journal
Volume	16
Issue number	32
DOIs	https://doi.org/10.1002/chem.201001174
Publication status	Published - 2010

Research Groups and Themes

Organic & Biological

Keywords

allylboration
asymmetric catalysis
borylation
dearomatization
lithiation
OXIDATIVE DEAROMATIZATION
ETA(2)-ARENE COMPLEXES
CHIRAL SECONDARY
NATURAL-PRODUCTS
ATE COMPLEXES
PENTAAMMINEOSMIUM(II)
CYCLOHEXENONES
HOMOLOGATION
CROTYLATION
DERIVATIVES

Access to Document

10.1002/chem.201001174

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NEW ASSYMETRIC REACTIONS AND THEIR APPLICATION IN TOTAL SYNTHESIS
Aggarwal, V. K. (Principal Investigator)
1/10/05 → 1/10/10
Project: Research

Cite this

@article{f811a5de62364134a13f200641109134,

title = "Benzylic Boron Reagents Behaving as Allylic Boron Reagents towards Aldehydes: A New Asymmetric Reaction Leading to Homoallylic Alcohols with Concomitant Dearomatisation",

keywords = "allylboration, asymmetric catalysis, borylation, dearomatization, lithiation, OXIDATIVE DEAROMATIZATION, ETA(2)-ARENE COMPLEXES, CHIRAL SECONDARY, NATURAL-PRODUCTS, ATE COMPLEXES, PENTAAMMINEOSMIUM(II), CYCLOHEXENONES, HOMOLOGATION, CROTYLATION, DERIVATIVES",

author = "\{Ros Lao\}, Abel and Antonio Bermejo and Aggarwal, \{Varinder K.\}",

year = "2010",

doi = "10.1002/chem.201001174",

language = "English",

volume = "16",

pages = "9741--9745",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "John Wiley and Sons Inc",

number = "32",

}

Benzylic Boron Reagents Behaving as Allylic Boron Reagents towards Aldehydes: A New Asymmetric Reaction Leading to Homoallylic Alcohols with Concomitant Dearomatisation. / Ros Lao, Abel; Bermejo, Antonio; Aggarwal, Varinder K.
In: Chemistry - A European Journal, Vol. 16, No. 32, 2010, p. 9741-9745.

Research output: Contribution to journal › Article (Academic Journal) › peer-review

TY - JOUR

T1 - Benzylic Boron Reagents Behaving as Allylic Boron Reagents towards Aldehydes

T2 - A New Asymmetric Reaction Leading to Homoallylic Alcohols with Concomitant Dearomatisation

AU - Ros Lao, Abel

AU - Bermejo, Antonio

AU - Aggarwal, Varinder K.

PY - 2010

Y1 - 2010

KW - allylboration

KW - asymmetric catalysis

KW - borylation

KW - dearomatization

KW - lithiation

KW - OXIDATIVE DEAROMATIZATION

KW - ETA(2)-ARENE COMPLEXES

KW - CHIRAL SECONDARY

KW - NATURAL-PRODUCTS

KW - ATE COMPLEXES

KW - PENTAAMMINEOSMIUM(II)

KW - CYCLOHEXENONES

KW - HOMOLOGATION

KW - CROTYLATION

KW - DERIVATIVES

U2 - 10.1002/chem.201001174

DO - 10.1002/chem.201001174

M3 - Article (Academic Journal)

C2 - 20589854

SN - 0947-6539

VL - 16

SP - 9741

EP - 9745

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 32

ER -

Benzylic Boron Reagents Behaving as Allylic Boron Reagents towards Aldehydes: A New Asymmetric Reaction Leading to Homoallylic Alcohols with Concomitant Dearomatisation

Research Groups and Themes

Keywords

Access to Document

Handle.net

Projects

NEW ASSYMETRIC REACTIONS AND THEIR APPLICATION IN TOTAL SYNTHESIS

Cite this