Projects per year
Abstract
Pinacolato boronyl ortho-silyl(hetero)aryltriflates are presented as a new class of building block for arylation. They demonstrate unique versatility by delivering boronate or (hetero)aryne reactivity chemoselectively for a notably broad reaction scope. This marks the unprecedented postfunctionalization of fluoride-activated
(hetero)aryne precursors, including as substrates in transition metal catalysis, and it offers valuable new arylboronate postfunctionalizations without use of specialized protecting groups.
(hetero)aryne precursors, including as substrates in transition metal catalysis, and it offers valuable new arylboronate postfunctionalizations without use of specialized protecting groups.
| Original language | English |
|---|---|
| Pages (from-to) | 11765-11769 |
| Number of pages | 5 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 54 |
| Issue number | 40 |
| DOIs | |
| Publication status | Published - 28 Sept 2015 |
Bibliographical note
Date of Acceptance: 14/07/2015Fingerprint
Dive into the research topics of 'Boryl (Hetero)aryne Precursors as Versatile Arylation Reagents: Synthesis via C-H Activation and Orthogonal Reactivity'. Together they form a unique fingerprint.Projects
- 1 Finished
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3-month Core Capability for Chemistry Research
Crosby, J. (Principal Investigator)
1/01/13 → 1/04/13
Project: Research
