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Bulk phase water diffusion is significantly inhibited by inhomogeneity of single non-crystal particle at low relative humidity

Research output: Contribution to journalArticle

  • Chen Cai
  • Stephen Ingram
  • Chunsheng Zhao
Original languageEnglish
Article number119595
Number of pages8
JournalJournal of Non-Crystalline Solids
Volume523
Early online date22 Aug 2019
DOIs
DateAccepted/In press - 2 Aug 2019
DateE-pub ahead of print - 22 Aug 2019
DatePublished (current) - 1 Nov 2019

Abstract

It has been suggested by recent studies that atmospheric particles adopt non-crystalline states which significantly impact aerosol-cloud interactions and atmospheric chemistry. In this study, the effect of non-crystalline states on water diffusion is detailed investigated from single multi-component particles levitated in aerosol optical tweezers. We infer the time-dependent particle size from Raman spectra using Mie fitting, thus derive the water diffusion coefficient (Dwater) from particle radius changes during evaporation or condensation processes. In both glassy states (in saccharide particles) and gel states (in MgSO4 particles), the bulk phase water diffusion is shown to be severely restricted, thus limiting the gas-particle water partitioning on the particle surface. The Dwater of glassy particles generally gradually decreases as the RH decreases, while the relative humidity (RH) - Dwater relationship of particle in gel state is complicated and brings huge deviation of Dwater determination. We therefore present the time dependent water content at different location (radial coordinate) of the particle. The time scale required for particle to get equilibrium to environmental RH is vastly extended by the kinetic inhibition of bulk phase water transfer. This can give direct and quantitative indication of water diffusion within single non-crystalline particle and its effect on gas-particle partitioning and equilibrium.

    Research areas

  • Atmospheric particle, Bulk phase inhomogeneity, Non-crystalline, Optical levitation measurement, Water transfer inhibition

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  • Full-text PDF (author’s accepted manuscript)

    Rights statement: This is the author accepted manuscript (AAM). The final published version (version of record) is available online via Elsevier at https://www.sciencedirect.com/science/article/pii/S0022309319304661 . Please refer to any applicable terms of use of the publisher.

    Accepted author manuscript, 839 KB, PDF document

    Embargo ends: 22/08/21

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    Licence: CC BY-NC-ND

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