Carbenoids from Primary Alkyl Chlorides by Heteroatom-Assisted Metallation

Jonathan Clayden; Marc Julia

doi:10.1055/s-1995-4849

Carbenoids from Primary Alkyl Chlorides by Heteroatom-Assisted Metallation

Jonathan Clayden, Marc Julia^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

9 Citations (Scopus)

Abstract

3-Chloroalkyl ethers can be deprotonated α to the chlorine atom at low temperatures, and the resulting carbenoids trapped intramolecularly to give α-halosilanes or cyclopropanes.

Original language	English
Pages (from-to)	103-104
Number of pages	2
Journal	SYNLETT
Volume	1995
Issue number	1
DOIs	https://doi.org/10.1055/s-1995-4849
Publication status	Published - 1 Jan 1995

Keywords

carbenoid
cyclopropane
LiC-KOR reagent
metallation
α-halosilane

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@article{1798d108dbac423490fcb0f924bed357,

title = "Carbenoids from Primary Alkyl Chlorides by Heteroatom-Assisted Metallation",

abstract = "3-Chloroalkyl ethers can be deprotonated α to the chlorine atom at low temperatures, and the resulting carbenoids trapped intramolecularly to give α-halosilanes or cyclopropanes.",

keywords = "carbenoid, cyclopropane, LiC-KOR reagent, metallation, α-halosilane",

author = "Jonathan Clayden and Marc Julia",

year = "1995",

month = jan,

day = "1",

doi = "10.1055/s-1995-4849",

language = "English",

volume = "1995",

pages = "103--104",

journal = "SYNLETT",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "1",

}

TY - JOUR

T1 - Carbenoids from Primary Alkyl Chlorides by Heteroatom-Assisted Metallation

AU - Clayden, Jonathan

AU - Julia, Marc

PY - 1995/1/1

Y1 - 1995/1/1

N2 - 3-Chloroalkyl ethers can be deprotonated α to the chlorine atom at low temperatures, and the resulting carbenoids trapped intramolecularly to give α-halosilanes or cyclopropanes.

AB - 3-Chloroalkyl ethers can be deprotonated α to the chlorine atom at low temperatures, and the resulting carbenoids trapped intramolecularly to give α-halosilanes or cyclopropanes.

KW - carbenoid

KW - cyclopropane

KW - LiC-KOR reagent

KW - metallation

KW - α-halosilane

UR - http://www.scopus.com/inward/record.url?scp=0043137875&partnerID=8YFLogxK

U2 - 10.1055/s-1995-4849

DO - 10.1055/s-1995-4849

M3 - Article (Academic Journal)

SN - 0936-5214

VL - 1995

SP - 103

EP - 104

JO - SYNLETT

JF - SYNLETT

IS - 1

ER -

Carbenoids from Primary Alkyl Chlorides by Heteroatom-Assisted Metallation

Abstract

Keywords

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