Carbenoids from Primary Alkyl Chlorides by Heteroatom-Assisted Metallation

Jonathan Clayden, Marc Julia*

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

8 Citations (Scopus)

Abstract

3-Chloroalkyl ethers can be deprotonated α to the chlorine atom at low temperatures, and the resulting carbenoids trapped intramolecularly to give α-halosilanes or cyclopropanes.

Original languageEnglish
Pages (from-to)103-104
Number of pages2
JournalSYNLETT
Volume1995
Issue number1
DOIs
Publication statusPublished - 1 Jan 1995

Keywords

  • carbenoid
  • cyclopropane
  • LiC-KOR reagent
  • metallation
  • α-halosilane

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