Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis

Alexander S. Henderson; John F. Bower; M. Carmen Galan

doi:10.1039/c4ob02056a

Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis

Alexander S. Henderson, John F. Bower^*, M. Carmen Galan

^*Corresponding author for this work

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Abstract

Versatile syntheses of C2-linked and C₂-symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl]₂ and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promising enantioselectivities.

Original language	English
Pages (from-to)	9180-9183
Number of pages	4
Journal	Organic and Biomolecular Chemistry
Volume	12
Issue number	45
Early online date	30 Sept 2014
DOIs	https://doi.org/10.1039/c4ob02056a
Publication status	Published - 7 Dec 2014

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10.1039/c4ob02056a

c4ob02056aFinal published version, 1.43 MBLicence: CC BY

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title = "Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis",

abstract = "Versatile syntheses of C2-linked and C2-symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl]2 and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promising enantioselectivities.",

author = "Henderson, {Alexander S.} and Bower, {John F.} and Galan, {M. Carmen}",

year = "2014",

month = dec,

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journal = "Organic and Biomolecular Chemistry",

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publisher = "Royal Society of Chemistry",

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AU - Henderson, Alexander S.

AU - Bower, John F.

AU - Galan, M. Carmen

PY - 2014/12/7

Y1 - 2014/12/7

N2 - Versatile syntheses of C2-linked and C2-symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl]2 and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promising enantioselectivities.

AB - Versatile syntheses of C2-linked and C2-symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl]2 and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promising enantioselectivities.

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U2 - 10.1039/c4ob02056a

DO - 10.1039/c4ob02056a

M3 - Article (Academic Journal)

C2 - 25296562

AN - SCOPUS:84908680774

SN - 1477-0520

VL - 12

SP - 9180

EP - 9183

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 45

ER -

Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis

Abstract

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Catalytic stereoselective synthesis of glycosides

3-month Core Capability for Chemistry Research

Reworking of Novel tools for Glycoscience

Cite this

Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis

Abstract

Structured keywords

Access to Document

Handle.net

Other files and links

Fingerprint

Projects

Catalytic stereoselective synthesis of glycosides

3-month Core Capability for Chemistry Research

Reworking of Novel tools for Glycoscience

Cite this