Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis

Alexander S. Henderson; John F. Bower; M. Carmen Galan

doi:10.1039/c4ob02056a

Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis

Alexander S. Henderson
, John F. Bower^*
, M. Carmen Galan

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

42 Citations (Scopus)

277 Downloads (Pure)

Abstract

Versatile syntheses of C2-linked and C₂-symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl]₂ and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promising enantioselectivities.

Original language	English
Pages (from-to)	9180-9183
Number of pages	4
Journal	Organic and Biomolecular Chemistry
Volume	12
Issue number	45
Early online date	30 Sept 2014
DOIs	https://doi.org/10.1039/c4ob02056a
Publication status	Published - 7 Dec 2014

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BCS and TECS CDTs
Organic & Biological

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10.1039/c4ob02056a

c4ob02056aFinal published version, 1.43 MBLicence: CC BY

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title = "Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis",

abstract = "Versatile syntheses of C2-linked and C2-symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl]2 and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promising enantioselectivities.",

author = "Henderson, \{Alexander S.\} and Bower, \{John F.\} and Galan, \{M. Carmen\}",

year = "2014",

month = dec,

day = "7",

doi = "10.1039/c4ob02056a",

language = "English",

volume = "12",

pages = "9180--9183",

journal = "Organic and Biomolecular Chemistry",

issn = "1477-0520",

publisher = "Royal Society of Chemistry",

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T1 - Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis

AU - Henderson, Alexander S.

AU - Bower, John F.

AU - Galan, M. Carmen

PY - 2014/12/7

Y1 - 2014/12/7

N2 - Versatile syntheses of C2-linked and C2-symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl]2 and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promising enantioselectivities.

AB - Versatile syntheses of C2-linked and C2-symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl]2 and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promising enantioselectivities.

UR - https://www.scopus.com/pages/publications/84908680774

U2 - 10.1039/c4ob02056a

DO - 10.1039/c4ob02056a

M3 - Article (Academic Journal)

C2 - 25296562

AN - SCOPUS:84908680774

SN - 1477-0520

VL - 12

SP - 9180

EP - 9183

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 45

ER -

Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis

Abstract

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Catalytic stereoselective synthesis of glycosides

3-month Core Capability for Chemistry Research

Reworking of Novel tools for Glycoscience

Cite this

Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis

Abstract

Research Groups and Themes

Access to Document

Handle.net

Other files and links

Fingerprint

Projects

Catalytic stereoselective synthesis of glycosides

3-month Core Capability for Chemistry Research

Reworking of Novel tools for Glycoscience

Cite this