Abstract
Rh‐catalyzed carbonylative C−C bond activation of cyclopropylamides generates configurationally stable rhodacyclopentanones that engage tethered alkenes in (3+1+2) cycloadditions. These studies provide the first examples of multicomponent cycloadditions that proceed through C−C bond activation of “simple” electron poor cyclopropanes.
Original language | English |
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Pages (from-to) | 221-225 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 58 |
Issue number | 1 |
Early online date | 29 Nov 2018 |
DOIs | |
Publication status | Published - 2 Jan 2019 |
Structured keywords
- BCS and TECS CDTs
Keywords
- C−C activation
- cycloaddition
- cyclopropane
- rhodium