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Carbonylative C-C Bond Activation of Electron-Poor Cyclopropanes: Rhodium‐Catalyzed (3+1+2) Cycloadditions of Cyclopropylamides

Research output: Contribution to journalArticle

Original languageEnglish
Pages (from-to)221-225
Number of pages5
JournalAngewandte Chemie - International Edition
Issue number1
Early online date29 Nov 2018
DateAccepted/In press - 5 Nov 2018
DateE-pub ahead of print - 29 Nov 2018
DatePublished (current) - 2 Jan 2019


Rh‐catalyzed carbonylative C−C bond activation of cyclopropylamides generates configurationally stable rhodacyclopentanones that engage tethered alkenes in (3+1+2) cycloadditions. These studies provide the first examples of multicomponent cycloadditions that proceed through C−C bond activation of “simple” electron poor cyclopropanes.

    Research areas

  • C−C activation, cycloaddition, cyclopropane, rhodium

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