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Carbonylative C-C Bond Activation of Electron-Poor Cyclopropanes: Rhodium‐Catalyzed (3+1+2) Cycloadditions of Cyclopropylamides

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Carbonylative C-C Bond Activation of Electron-Poor Cyclopropanes : Rhodium‐Catalyzed (3+1+2) Cycloadditions of Cyclopropylamides. / Dalling, Andrew; Yamauchi, Takayuki; McCreanor, Niall; Cox, Lydia; Bower, John.

In: Angewandte Chemie - International Edition, Vol. 58, No. 1, 02.01.2019, p. 221-225.

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Dalling, Andrew ; Yamauchi, Takayuki ; McCreanor, Niall ; Cox, Lydia ; Bower, John. / Carbonylative C-C Bond Activation of Electron-Poor Cyclopropanes : Rhodium‐Catalyzed (3+1+2) Cycloadditions of Cyclopropylamides. In: Angewandte Chemie - International Edition. 2019 ; Vol. 58, No. 1. pp. 221-225.

Bibtex

@article{86fef2ebce284ee39f49c2277a8d4e22,
title = "Carbonylative C-C Bond Activation of Electron-Poor Cyclopropanes: Rhodium‐Catalyzed (3+1+2) Cycloadditions of Cyclopropylamides",
abstract = "Rh‐catalyzed carbonylative C−C bond activation of cyclopropylamides generates configurationally stable rhodacyclopentanones that engage tethered alkenes in (3+1+2) cycloadditions. These studies provide the first examples of multicomponent cycloadditions that proceed through C−C bond activation of “simple” electron poor cyclopropanes.",
keywords = "C−C activation, cycloaddition, cyclopropane, rhodium",
author = "Andrew Dalling and Takayuki Yamauchi and Niall McCreanor and Lydia Cox and John Bower",
year = "2019",
month = "1",
day = "2",
doi = "10.1002/anie.201811460",
language = "English",
volume = "58",
pages = "221--225",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "Wiley-VCH Verlag",
number = "1",

}

RIS - suitable for import to EndNote

TY - JOUR

T1 - Carbonylative C-C Bond Activation of Electron-Poor Cyclopropanes

T2 - Rhodium‐Catalyzed (3+1+2) Cycloadditions of Cyclopropylamides

AU - Dalling, Andrew

AU - Yamauchi, Takayuki

AU - McCreanor, Niall

AU - Cox, Lydia

AU - Bower, John

PY - 2019/1/2

Y1 - 2019/1/2

N2 - Rh‐catalyzed carbonylative C−C bond activation of cyclopropylamides generates configurationally stable rhodacyclopentanones that engage tethered alkenes in (3+1+2) cycloadditions. These studies provide the first examples of multicomponent cycloadditions that proceed through C−C bond activation of “simple” electron poor cyclopropanes.

AB - Rh‐catalyzed carbonylative C−C bond activation of cyclopropylamides generates configurationally stable rhodacyclopentanones that engage tethered alkenes in (3+1+2) cycloadditions. These studies provide the first examples of multicomponent cycloadditions that proceed through C−C bond activation of “simple” electron poor cyclopropanes.

KW - C−C activation

KW - cycloaddition

KW - cyclopropane

KW - rhodium

UR - http://www.scopus.com/inward/record.url?scp=85057810891&partnerID=8YFLogxK

U2 - 10.1002/anie.201811460

DO - 10.1002/anie.201811460

M3 - Article

VL - 58

SP - 221

EP - 225

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 1

ER -