CATALYTIC ASYMMETRIC HYDROBORATION WITH OXAZABOROLIDINES

J M  BROWN; Guy C Lloyd-Jones

CATALYTIC ASYMMETRIC HYDROBORATION WITH OXAZABOROLIDINES

J M BROWN
, Guy C Lloyd-Jones

School of Chemistry

Research output: Contribution to journal › Comment/debate (Academic Journal) › peer-review

70 Citations (Scopus)

Abstract

The cyclic secondary boranes derived from ephedrine and pseudoephedrine undergo rhodium complex-catalysed hydroboration of styrenes; both the regiochemistry and derived enantiomeric excess depend strongly on the structure of the catalyst with the ferrocenebiphosphine complex (12d) the most promising to date.

Original language	English
Pages (from-to)	869-872
Number of pages	4
Journal	Tetrahedron: Asymmetry
Volume	1
Issue number	12
Publication status	Published - 1990

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title = "CATALYTIC ASYMMETRIC HYDROBORATION WITH OXAZABOROLIDINES",

abstract = "The cyclic secondary boranes derived from ephedrine and pseudoephedrine undergo rhodium complex-catalysed hydroboration of styrenes; both the regiochemistry and derived enantiomeric excess depend strongly on the structure of the catalyst with the ferrocenebiphosphine complex (12d) the most promising to date.",

author = "BROWN, \{J M\} and Lloyd-Jones, \{Guy C\}",

year = "1990",

language = "English",

volume = "1",

pages = "869--872",

journal = "Tetrahedron: Asymmetry",

issn = "0957-4166",

publisher = "Elsevier Limited",

number = "12",

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TY - JOUR

T1 - CATALYTIC ASYMMETRIC HYDROBORATION WITH OXAZABOROLIDINES

AU - BROWN, J M

AU - Lloyd-Jones, Guy C

PY - 1990

Y1 - 1990

N2 - The cyclic secondary boranes derived from ephedrine and pseudoephedrine undergo rhodium complex-catalysed hydroboration of styrenes; both the regiochemistry and derived enantiomeric excess depend strongly on the structure of the catalyst with the ferrocenebiphosphine complex (12d) the most promising to date.

AB - The cyclic secondary boranes derived from ephedrine and pseudoephedrine undergo rhodium complex-catalysed hydroboration of styrenes; both the regiochemistry and derived enantiomeric excess depend strongly on the structure of the catalyst with the ferrocenebiphosphine complex (12d) the most promising to date.

M3 - Comment/debate (Academic Journal)

SN - 0957-4166

VL - 1

SP - 869

EP - 872

JO - Tetrahedron: Asymmetry

JF - Tetrahedron: Asymmetry

IS - 12

ER -

CATALYTIC ASYMMETRIC HYDROBORATION WITH OXAZABOROLIDINES

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