Cationic gold(I) complexes of 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene

Nell S. Townsend; Michael Green; Chris Russell

doi:10.1021/om201265n

Cationic gold(I) complexes of 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene

Nell S. Townsend, Michael Green, Chris Russell

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

16 Citations (Scopus)

Abstract

2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene forms η ¹ complexes with [AuL] ⁺. Significant structural differences are observed between the P ₃(C ^tBu) ₃ units, depending on the auxiliary ligand bound to gold. For L = NHC, a planar P ₃(C ^tBu) ₃ is observed; for L = P( ^tBu) ₂(o-biphenyl), the P ₃(C ^tBu) ₃ ligand is significantly puckered in the solid state. NICS computations on model complexes suggest this puckering only has a minor effect on the aromaticity of the heterocyclic ring.

Original language	English
Pages (from-to)	2543-2545
Number of pages	3
Journal	Organometallics
Volume	31
Issue number	7
DOIs	https://doi.org/10.1021/om201265n
Publication status	Published - 9 Apr 2012

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Inorganic & Materials

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title = "Cationic gold(I) complexes of 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene",

abstract = "2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene forms η 1 complexes with [AuL] +. Significant structural differences are observed between the P 3(C tBu) 3 units, depending on the auxiliary ligand bound to gold. For L = NHC, a planar P 3(C tBu) 3 is observed; for L = P( tBu) 2(o-biphenyl), the P 3(C tBu) 3 ligand is significantly puckered in the solid state. NICS computations on model complexes suggest this puckering only has a minor effect on the aromaticity of the heterocyclic ring.",

author = "Townsend, \{Nell S.\} and Michael Green and Chris Russell",

year = "2012",

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day = "9",

doi = "10.1021/om201265n",

language = "English",

volume = "31",

pages = "2543--2545",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Cationic gold(I) complexes of 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene

AU - Townsend, Nell S.

AU - Green, Michael

AU - Russell, Chris

PY - 2012/4/9

Y1 - 2012/4/9

N2 - 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene forms η 1 complexes with [AuL] +. Significant structural differences are observed between the P 3(C tBu) 3 units, depending on the auxiliary ligand bound to gold. For L = NHC, a planar P 3(C tBu) 3 is observed; for L = P( tBu) 2(o-biphenyl), the P 3(C tBu) 3 ligand is significantly puckered in the solid state. NICS computations on model complexes suggest this puckering only has a minor effect on the aromaticity of the heterocyclic ring.

AB - 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene forms η 1 complexes with [AuL] +. Significant structural differences are observed between the P 3(C tBu) 3 units, depending on the auxiliary ligand bound to gold. For L = NHC, a planar P 3(C tBu) 3 is observed; for L = P( tBu) 2(o-biphenyl), the P 3(C tBu) 3 ligand is significantly puckered in the solid state. NICS computations on model complexes suggest this puckering only has a minor effect on the aromaticity of the heterocyclic ring.

UR - http://www.scopus.com/inward/record.url?scp=84859594102&partnerID=8YFLogxK

U2 - 10.1021/om201265n

DO - 10.1021/om201265n

M3 - Article (Academic Journal)

AN - SCOPUS:84859594102

SN - 0276-7333

VL - 31

SP - 2543

EP - 2545

JO - Organometallics

JF - Organometallics

IS - 7

ER -

Cationic gold(I) complexes of 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene

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