Abstract
The cationic cages nido-[C2But2P2E]+ (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.
Translated title of the contribution | Cationic phosphorus-carbon-pnictogen cages isolobal to [C5R5]+ |
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Original language | English |
Pages (from-to) | 1375 - 1377 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 13 |
DOIs | |
Publication status | Published - 2006 |