Cationic phosphorus-carbon-pnictogen cages isolobal to [C5R5]+

C Fish, M Green, JC Jeffery, RJ Kilby, JM Lynam, JE McGrady, DA Pantazis, CA Russell, CE Willans

Research output: Contribution to journalArticle (Academic Journal)

25 Citations (Scopus)

Abstract

The cationic cages nido-[C2But2P2E]+ (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.
Original languageEnglish
Pages (from-to)1375 - 1377
Number of pages3
JournalChemical Communications
Volume13
DOIs
Publication statusPublished - 2006

Bibliographical note

Publisher: Royal Society of Chemistry

Fingerprint Dive into the research topics of 'Cationic phosphorus-carbon-pnictogen cages isolobal to [C<sub>5</sub>R<sub>5</sub>]<sup>+</sup>'. Together they form a unique fingerprint.

  • Cite this

    Fish, C., Green, M., Jeffery, JC., Kilby, RJ., Lynam, JM., McGrady, JE., Pantazis, DA., Russell, CA., & Willans, CE. (2006). Cationic phosphorus-carbon-pnictogen cages isolobal to [C5R5]+. Chemical Communications, 13, 1375 - 1377. https://doi.org/10.1039/b517710c