Cationic phosphorus-carbon-pnictogen cages isolobal to [C5R5]+

C Fish; M Green; JC Jeffery; RJ Kilby; JM Lynam; JE McGrady; DA Pantazis; CA Russell; CE Willans

doi:10.1039/b517710c

Cationic phosphorus-carbon-pnictogen cages isolobal to [C₅R₅]⁺

C Fish, M Green, JC Jeffery, RJ Kilby, JM Lynam, JE McGrady, DA Pantazis, CA Russell, CE Willans

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

31 Citations (Scopus)

Abstract

The cationic cages nido-[C2But2P2E]+ (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.

Translated title of the contribution	Cationic phosphorus-carbon-pnictogen cages isolobal to [C₅R₅]⁺
Original language	English
Pages (from-to)	1375 - 1377
Number of pages	3
Journal	Chemical Communications
Volume	13
DOIs	https://doi.org/10.1039/b517710c
Publication status	Published - 2006

Bibliographical note

Publisher: Royal Society of Chemistry

Research Groups and Themes

Inorganic & Materials

Access to Document

10.1039/b517710c

http://dx.doi.org/10.1039/b517710c

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Cite this

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title = "Cationic phosphorus-carbon-pnictogen cages isolobal to [C5R5]+",

abstract = "The cationic cages nido-[C2But2P2E]+ (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.",

author = "C Fish and M Green and JC Jeffery and RJ Kilby and JM Lynam and JE McGrady and DA Pantazis and CA Russell and CE Willans",

note = "Publisher: Royal Society of Chemistry",

year = "2006",

doi = "10.1039/b517710c",

language = "English",

volume = "13",

pages = "1375 -- 1377",

journal = "Chemical Communications",

issn = "1364-548X",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Cationic phosphorus-carbon-pnictogen cages isolobal to [C5R5]+

AU - Fish, C

AU - Green, M

AU - Jeffery, JC

AU - Kilby, RJ

AU - Lynam, JM

AU - McGrady, JE

AU - Pantazis, DA

AU - Russell, CA

AU - Willans, CE

N1 - Publisher: Royal Society of Chemistry

PY - 2006

Y1 - 2006

N2 - The cationic cages nido-[C2But2P2E]+ (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.

AB - The cationic cages nido-[C2But2P2E]+ (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.

U2 - 10.1039/b517710c

DO - 10.1039/b517710c

M3 - Article (Academic Journal)

SN - 1364-548X

SN - 2050-5639

VL - 13

SP - 1375

EP - 1377

JO - Chemical Communications

JF - Chemical Communications

ER -