Chemical communication: Conductors and insulators of screw-sense preference between helical oligo(aminoisobutyric acid) domains

Thomas Boddaert; Jordi Solà; Madeleine Helliwell; Jonathan Clayden

doi:10.1039/c2cc00060a

Chemical communication: Conductors and insulators of screw-sense preference between helical oligo(aminoisobutyric acid) domains

Thomas Boddaert, Jordi Solà, Madeleine Helliwell, Jonathan Clayden^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal)

31 Citations (Scopus)

Abstract

¹H NMR studies quantify the abilities of achiral amino acids to communicate a left-handed screw-sense preference from one helical Aib ₄ domain to another: certain quaternary amino acids (e.g. Ac ₆c) act as effective conductors of conformational preference while others (e.g. diphenylglycine) acts as insulators.

Original language	English
Pages (from-to)	3397-3399
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	28
Early online date	31 Jan 2012
DOIs	https://doi.org/10.1039/c2cc00060a
Publication status	Published - 7 Apr 2012

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abstract = " 1H NMR studies quantify the abilities of achiral amino acids to communicate a left-handed screw-sense preference from one helical Aib 4 domain to another: certain quaternary amino acids (e.g. Ac 6c) act as effective conductors of conformational preference while others (e.g. diphenylglycine) acts as insulators.",

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AB - 1H NMR studies quantify the abilities of achiral amino acids to communicate a left-handed screw-sense preference from one helical Aib 4 domain to another: certain quaternary amino acids (e.g. Ac 6c) act as effective conductors of conformational preference while others (e.g. diphenylglycine) acts as insulators.

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