Chemical communication: Conductors and insulators of screw-sense preference between helical oligo(aminoisobutyric acid) domains

Thomas Boddaert; Jordi Solà; Madeleine Helliwell; Jonathan Clayden

doi:10.1039/c2cc00060a

Chemical communication: Conductors and insulators of screw-sense preference between helical oligo(aminoisobutyric acid) domains

Thomas Boddaert
, Jordi Solà
, Madeleine Helliwell
, Jonathan Clayden^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

37 Citations (Scopus)

Abstract

¹H NMR studies quantify the abilities of achiral amino acids to communicate a left-handed screw-sense preference from one helical Aib ₄ domain to another: certain quaternary amino acids (e.g. Ac ₆c) act as effective conductors of conformational preference while others (e.g. diphenylglycine) acts as insulators.

Original language	English
Pages (from-to)	3397-3399
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	28
Early online date	31 Jan 2012
DOIs	https://doi.org/10.1039/c2cc00060a
Publication status	Published - 7 Apr 2012

Research Groups and Themes

Organic & Biological

Access to Document

10.1039/c2cc00060a

Handle.net

Persistent link

Cite this

@article{f3e13d57173f47b0900f962422618eea,

title = "Chemical communication: Conductors and insulators of screw-sense preference between helical oligo(aminoisobutyric acid) domains",

abstract = " 1H NMR studies quantify the abilities of achiral amino acids to communicate a left-handed screw-sense preference from one helical Aib 4 domain to another: certain quaternary amino acids (e.g. Ac 6c) act as effective conductors of conformational preference while others (e.g. diphenylglycine) acts as insulators.",

author = "Thomas Boddaert and Jordi Sol{\`a} and Madeleine Helliwell and Jonathan Clayden",

year = "2012",

month = apr,

day = "7",

doi = "10.1039/c2cc00060a",

language = "English",

volume = "48",

pages = "3397--3399",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "28",

}

TY - JOUR

T1 - Chemical communication

T2 - Conductors and insulators of screw-sense preference between helical oligo(aminoisobutyric acid) domains

AU - Boddaert, Thomas

AU - Solà, Jordi

AU - Helliwell, Madeleine

AU - Clayden, Jonathan

PY - 2012/4/7

Y1 - 2012/4/7

N2 - 1H NMR studies quantify the abilities of achiral amino acids to communicate a left-handed screw-sense preference from one helical Aib 4 domain to another: certain quaternary amino acids (e.g. Ac 6c) act as effective conductors of conformational preference while others (e.g. diphenylglycine) acts as insulators.

AB - 1H NMR studies quantify the abilities of achiral amino acids to communicate a left-handed screw-sense preference from one helical Aib 4 domain to another: certain quaternary amino acids (e.g. Ac 6c) act as effective conductors of conformational preference while others (e.g. diphenylglycine) acts as insulators.

UR - https://www.scopus.com/pages/publications/84857837907

U2 - 10.1039/c2cc00060a

DO - 10.1039/c2cc00060a

M3 - Article (Academic Journal)

C2 - 22363936

AN - SCOPUS:84857837907

SN - 1359-7345

VL - 48

SP - 3397

EP - 3399

JO - Chemical Communications

JF - Chemical Communications

IS - 28

ER -

Chemical communication: Conductors and insulators of screw-sense preference between helical oligo(aminoisobutyric acid) domains

Abstract

Research Groups and Themes

Access to Document

Handle.net

Other files and links

Fingerprint

Cite this