Complete Stereoretention in the Rhodium-Catalyzed 1,2-Addition of Chiral Secondary and Tertiary Alkyl Potassium Trifluoroborate Salts to Aldehydes

Abel Ros Lao, Varinder K. Aggarwal*

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

66 Citations (Scopus)
Original languageEnglish
Pages (from-to)6289-6292
Number of pages4
JournalAngewandte Chemie - International Edition
Volume48
Issue number34
DOIs
Publication statusPublished - 2009

Keywords

  • 1,2-addition
  • alkyl trifluoroborate salts
  • chirality
  • homogeneous catalysis
  • rhodium
  • CROSS-COUPLING REACTIONS
  • ARYLBORONIC ACIDS
  • GRIGNARD-REAGENTS
  • ASYMMETRIC 1,4-ADDITION
  • ALKENYLBORONIC ACIDS
  • CONFIGURATIONAL STABILITY
  • RECEPTOR ANTAGONIST
  • ORGANOBORONIC ACIDS
  • AROMATIC-ALDEHYDES
  • NEGISHI REACTIONS

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