Complexation of stable carbenes with alkali metals

Roger W. Alder; Michael E. Blake; Christel Bortolotti; Simone Bufali; Craig P. Butts; Emma Linehan; Josep M. Oliva; A. Guy Orpen; Michael J. Quayle

doi:10.1039/a808951e

Complexation of stable carbenes with alkali metals

Roger W. Alder^*, Michael E. Blake, Christel Bortolotti, Simone Bufali, Craig P. Butts, Emma Linehan, Josep M. Oliva, A. Guy Orpen, Michael J. Quayle

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

217 Citations (Scopus)

Abstract

Stable diaminocarbenes, including imidazol-2-ylidenes, undergo complexation with lithium, sodium and potassium species; the crystal structure of a complex of 1,3-diisopropyl-3,4,5,6-tetrahydropyrimid-2-ylidene 1 with KN(SiMe₃)₂ is reported.

Translated title of the contribution	Complexation of stable carbenes with alkali metals
Original language	English
Pages (from-to)	241-242
Number of pages	2
Journal	Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/a808951e
Publication status	Published - 7 Feb 1999

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title = "Complexation of stable carbenes with alkali metals",

abstract = "Stable diaminocarbenes, including imidazol-2-ylidenes, undergo complexation with lithium, sodium and potassium species; the crystal structure of a complex of 1,3-diisopropyl-3,4,5,6-tetrahydropyrimid-2-ylidene 1 with KN(SiMe3)2 is reported.",

author = "Alder, {Roger W.} and Blake, {Michael E.} and Christel Bortolotti and Simone Bufali and Butts, {Craig P.} and Emma Linehan and Oliva, {Josep M.} and Orpen, {A. Guy} and Quayle, {Michael J.}",

year = "1999",

month = feb,

day = "7",

doi = "10.1039/a808951e",

language = "English",

pages = "241--242",

journal = "Chemical Communications",

issn = "1364-548X",

publisher = "Royal Society of Chemistry",

number = "3",

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TY - JOUR

T1 - Complexation of stable carbenes with alkali metals

AU - Alder, Roger W.

AU - Blake, Michael E.

AU - Bortolotti, Christel

AU - Bufali, Simone

AU - Butts, Craig P.

AU - Linehan, Emma

AU - Oliva, Josep M.

AU - Orpen, A. Guy

AU - Quayle, Michael J.

PY - 1999/2/7

Y1 - 1999/2/7

N2 - Stable diaminocarbenes, including imidazol-2-ylidenes, undergo complexation with lithium, sodium and potassium species; the crystal structure of a complex of 1,3-diisopropyl-3,4,5,6-tetrahydropyrimid-2-ylidene 1 with KN(SiMe3)2 is reported.

AB - Stable diaminocarbenes, including imidazol-2-ylidenes, undergo complexation with lithium, sodium and potassium species; the crystal structure of a complex of 1,3-diisopropyl-3,4,5,6-tetrahydropyrimid-2-ylidene 1 with KN(SiMe3)2 is reported.

UR - http://www.scopus.com/inward/record.url?scp=0033531376&partnerID=8YFLogxK

U2 - 10.1039/a808951e

DO - 10.1039/a808951e

M3 - Article (Academic Journal)

SN - 1364-548X

SP - 241

EP - 242

JO - Chemical Communications

JF - Chemical Communications

IS - 3

ER -

Complexation of stable carbenes with alkali metals

Abstract

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