Composites of Kaolin and Polydimethylsiloxane

Yan Zhang, David I. Gittins, David Skuse, Terence Cosgrove, Jeroen S. van Duijneveldt

Research output: Contribution to journalArticle (Academic Journal)peer-review

8 Citations (Scopus)

Abstract

Kaolin particles were surface-treated with isobutyltrimethoxysilane (IBTMS), hydrogenated tallow (HT), and a polyisobutyl chain-based stabilizer (SAP) to make composites with polydimethylsiloxane (PDMS). IBTMS did not cover the strong acid sites on the kaolin surface and as a result a cross-linking reaction occurred for silanol-terminated PDMS. The polyisobutyl chain of SAP was found to be incompatible with PDMS and this caused aggregation of the kaolin particles. HT was the most effective at dispersing the particles into silanol-terminated PDMS. The aggregation state of the composites was characterized using rheology and microscopy. Both showed the HT-treated particles were well-dispersed in low molecular weight silanol-terminated PDMS, and they were weakly flocculated in higher molecular weight silanol-terminated PDMS. However, the same particles aggregated when dispersed in methyl-terminated PDMS. It appears the silanol-terminated PDMS acted as costabilizer through interaction with the kaolin surface. Transverse relaxation NMR was used to probe mobility of the PDMS chains in the composites. This showed little dependence on surface treatment, aggregation state, or polymer end groups. For all samples, chain mobility decreased with increasing kaolin concentration.

Original languageEnglish
Pages (from-to)12032-12039
Number of pages8
JournalLangmuir
Volume24
Issue number20
DOIs
Publication statusPublished - 21 Oct 2008

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