Concerted rotation in a tertiary aromatic amide: Towards a simple molecular gear

Jonathan Clayden; Jennifer H. Pink

doi:10.1002/(SICI)1521-3773(19980803)37:13/14<1937::AID-ANIE1937>3.0.CO;2-4

Concerted rotation in a tertiary aromatic amide: Towards a simple molecular gear

Jonathan Clayden^*, Jennifer H. Pink

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

112 Citations (Scopus)

Abstract

At least 90% of the rotations about the Ar-CO bond in amide 1 are concerted with rotation about the C-N bond. As a result, 1 demonstrates features of a simple molecular gear.

Original language	English
Pages (from-to)	1937-1939
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	37
Issue number	13-14
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19980803)37:13/14<1937::AID-ANIE1937>3.0.CO;2-4
Publication status	Published - 3 Aug 1998

Keywords

Amides
Atropisomerism
Molecular devices
Molecular dynamics

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title = "Concerted rotation in a tertiary aromatic amide: Towards a simple molecular gear",

abstract = "At least 90% of the rotations about the Ar-CO bond in amide 1 are concerted with rotation about the C-N bond. As a result, 1 demonstrates features of a simple molecular gear.",

keywords = "Amides, Atropisomerism, Molecular devices, Molecular dynamics",

author = "Jonathan Clayden and Pink, {Jennifer H.}",

year = "1998",

month = aug,

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doi = "10.1002/(SICI)1521-3773(19980803)37:13/14<1937::AID-ANIE1937>3.0.CO;2-4",

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AU - Clayden, Jonathan

AU - Pink, Jennifer H.

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N2 - At least 90% of the rotations about the Ar-CO bond in amide 1 are concerted with rotation about the C-N bond. As a result, 1 demonstrates features of a simple molecular gear.

AB - At least 90% of the rotations about the Ar-CO bond in amide 1 are concerted with rotation about the C-N bond. As a result, 1 demonstrates features of a simple molecular gear.

KW - Amides

KW - Atropisomerism

KW - Molecular devices

KW - Molecular dynamics

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U2 - 10.1002/(SICI)1521-3773(19980803)37:13/14<1937::AID-ANIE1937>3.0.CO;2-4

DO - 10.1002/(SICI)1521-3773(19980803)37:13/14<1937::AID-ANIE1937>3.0.CO;2-4

M3 - Article (Academic Journal)

AN - SCOPUS:0032479733

SN - 1433-7851

VL - 37

SP - 1937

EP - 1939

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 13-14

ER -

Concerted rotation in a tertiary aromatic amide: Towards a simple molecular gear

Abstract

Keywords

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