Conformational studies of tertiary oligo-m-benzanilides and oligo-p-benzanilides in solution

Laurent Chabaud, Jonathan Clayden*, Madeleine Helliwell, Abigail Page, James Raftery, Lluís Vallverdú

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

22 Citations (Scopus)

Abstract

A series of oligo-m- and p-benzanilides were made and their conformations in solution were studied by NMR. In most cases, conformational mixtures were observed as soon as three or more monomers were incorporated into the oligomer. Some crystal structures were obtained, which indicated that helical conformations were adopted in the solid state.

Original languageEnglish
Pages (from-to)6936-6957
Number of pages22
JournalTetrahedron
Volume66
Issue number34
Early online date18 Jun 2010
DOIs
Publication statusPublished - 21 Aug 2010

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