Conjunctive functionalization of vinyl boronate complexes with electrophiles: A diastereoselective three-component coupling

Roly J. Armstrong, Christopher Sandford, Cristina García-Ruiz, Varinder K. Aggarwal*

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

20 Citations (Scopus)
247 Downloads (Pure)

Abstract

A method for the conjunctive functionalization of vinyl boronate complexes with electrophiles is described. The overall process represents a three-component coupling between a vinyl boronic ester, carbon nucleophile and an electrophile, thus affording complex multifunctionalized products from simple starting materials. The diastereoselectivity (syn or anti) of this process is strongly dependent upon the nature of the electrophile.

Original languageEnglish
Pages (from-to)4922-4925
Number of pages4
JournalChemical Communications
Volume53
Issue number36
Early online date20 Apr 2017
DOIs
Publication statusPublished - 20 Apr 2017

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