Continuous structural evolution of calcium carbonate particles: a unifying model of copolymer-mediated crystallization

A Kulak, P Iddon, Y Li, S Armes, H Cölfen, O Paris, RM Wilson, FC Meldrum

Research output: Contribution to journalArticle (Academic Journal)peer-review

229 Citations (Scopus)

Abstract

Two double-hydrophilic block copolymers, each comprising a nonionic block and an anionic block comprising pendent aromatic sulfonate groups, were used as additives to modify the crystallization of CaCO3. Marked morphological changes in the CaCO3 particles were observed depending on the reaction conditions used. A poly(ethylene oxide)-b-poly(sodium 4-styrenesulfonate) diblock copolymer was particularly versatile in effecting a morphological change in calcite particles, and a continuous structural transition in the product particles from polycrystalline to mesocrystal to single crystal was observed with variation in the calcium concentration. The existence of this structural sequence provides unique insight into the mechanism of polymer-mediated crystallization. We propose that it reflects continuity in the crystallization mechanism itself, spanning the limits from nonoriented aggregation of nanoparticles to classical ion-by-ion growth. The various pathways to polycrystalline, mesocrystal, and single-crystal particles, which had previously been considered to be distinct, therefore all form part of a unifying crystallization framework based on the aggregation of precursor subunits.
Translated title of the contributionContinuous structural evolution of calcium carbonate particles: a unifying model of copolymer-mediated crystallization
Original languageEnglish
Pages (from-to)3729 - 3736
Number of pages8
JournalJournal of the American Chemical Society
Volume129 (12)
DOIs
Publication statusPublished - Mar 2007

Bibliographical note

Publisher: American Chemical Society
Other identifier: IDS Number 147YI

Fingerprint Dive into the research topics of 'Continuous structural evolution of calcium carbonate particles: a unifying model of copolymer-mediated crystallization'. Together they form a unique fingerprint.

Cite this