Controlled thiol-ene post-polymerization reactions on polyferrocenylsilane homopolymers and block copolymers

Laurent Chabanne; Stefan Pfirrmann; David J. Lunn; Ian Manners

doi:10.1039/c3py21129k

Controlled thiol-ene post-polymerization reactions on polyferrocenylsilane homopolymers and block copolymers

Laurent Chabanne, Stefan Pfirrmann, David J. Lunn, Ian Manners^*

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

26 Citations (Scopus)

Abstract

Various thiols were reacted with poly(ferrocenylmethylvinylsilane) (PFMVS) homopolymers using the radical-mediated thiol-ene reaction with a view to preparing metallopolymers with diverse functional groups. Post-polymerization thiol-ene reactions on poly(ferrocenyldimethylsilane)-b- poly(ferrocenylmethylvinylsilane) (PFDMS-b-PFMVS) diblock copolymers with dodecanethiol and octadecanethiol afforded diblocks with a long hexane-soluble block and a short crystalline, hexane-insoluble PFDMS block. The thiol-ene reactions provided sufficient control to allow access to diblocks that were partially substituted, thus leaving vinyl groups that might subsequently be used for further post-polymerization reactions. © 2013 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	2353-2360
Number of pages	8
Journal	Polymer Chemistry
Volume	4
Issue number	7
DOIs	https://doi.org/10.1039/c3py21129k
Publication status	Published - 7 Apr 2013

Research Groups and Themes

BCS and TECS CDTs

Keywords

RING-OPENING POLYMERIZATION
DIBLOCK COPOLYMERS
CYLINDRICAL MICELLES
CRYSTALLINE-CORE
CLICK CHEMISTRY
CONTROLLED LENGTH
MORPHOLOGIES
SILICON
ARCHITECTURES
EFFICIENT

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title = "Controlled thiol-ene post-polymerization reactions on polyferrocenylsilane homopolymers and block copolymers",

abstract = "Various thiols were reacted with poly(ferrocenylmethylvinylsilane) (PFMVS) homopolymers using the radical-mediated thiol-ene reaction with a view to preparing metallopolymers with diverse functional groups. Post-polymerization thiol-ene reactions on poly(ferrocenyldimethylsilane)-b- poly(ferrocenylmethylvinylsilane) (PFDMS-b-PFMVS) diblock copolymers with dodecanethiol and octadecanethiol afforded diblocks with a long hexane-soluble block and a short crystalline, hexane-insoluble PFDMS block. The thiol-ene reactions provided sufficient control to allow access to diblocks that were partially substituted, thus leaving vinyl groups that might subsequently be used for further post-polymerization reactions. {\textcopyright} 2013 The Royal Society of Chemistry.",

keywords = "RING-OPENING POLYMERIZATION, DIBLOCK COPOLYMERS, CYLINDRICAL MICELLES, CRYSTALLINE-CORE, CLICK CHEMISTRY, CONTROLLED LENGTH, MORPHOLOGIES, SILICON, ARCHITECTURES, EFFICIENT",

author = "Laurent Chabanne and Stefan Pfirrmann and Lunn, {David J.} and Ian Manners",

year = "2013",

month = apr,

day = "7",

doi = "10.1039/c3py21129k",

language = "English",

volume = "4",

pages = "2353--2360",

journal = "Polymer Chemistry",

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TY - JOUR

T1 - Controlled thiol-ene post-polymerization reactions on polyferrocenylsilane homopolymers and block copolymers

AU - Chabanne, Laurent

AU - Pfirrmann, Stefan

AU - Lunn, David J.

AU - Manners, Ian

PY - 2013/4/7

Y1 - 2013/4/7

N2 - Various thiols were reacted with poly(ferrocenylmethylvinylsilane) (PFMVS) homopolymers using the radical-mediated thiol-ene reaction with a view to preparing metallopolymers with diverse functional groups. Post-polymerization thiol-ene reactions on poly(ferrocenyldimethylsilane)-b- poly(ferrocenylmethylvinylsilane) (PFDMS-b-PFMVS) diblock copolymers with dodecanethiol and octadecanethiol afforded diblocks with a long hexane-soluble block and a short crystalline, hexane-insoluble PFDMS block. The thiol-ene reactions provided sufficient control to allow access to diblocks that were partially substituted, thus leaving vinyl groups that might subsequently be used for further post-polymerization reactions. © 2013 The Royal Society of Chemistry.

AB - Various thiols were reacted with poly(ferrocenylmethylvinylsilane) (PFMVS) homopolymers using the radical-mediated thiol-ene reaction with a view to preparing metallopolymers with diverse functional groups. Post-polymerization thiol-ene reactions on poly(ferrocenyldimethylsilane)-b- poly(ferrocenylmethylvinylsilane) (PFDMS-b-PFMVS) diblock copolymers with dodecanethiol and octadecanethiol afforded diblocks with a long hexane-soluble block and a short crystalline, hexane-insoluble PFDMS block. The thiol-ene reactions provided sufficient control to allow access to diblocks that were partially substituted, thus leaving vinyl groups that might subsequently be used for further post-polymerization reactions. © 2013 The Royal Society of Chemistry.

KW - RING-OPENING POLYMERIZATION

KW - DIBLOCK COPOLYMERS

KW - CYLINDRICAL MICELLES

KW - CRYSTALLINE-CORE

KW - CLICK CHEMISTRY

KW - CONTROLLED LENGTH

KW - MORPHOLOGIES

KW - SILICON

KW - ARCHITECTURES

KW - EFFICIENT

UR - http://www.scopus.com/inward/record.url?scp=84874906534&partnerID=8YFLogxK

U2 - 10.1039/c3py21129k

DO - 10.1039/c3py21129k

M3 - Article (Academic Journal)

SN - 1759-9954

VL - 4

SP - 2353

EP - 2360

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 7

ER -

Controlled thiol-ene post-polymerization reactions on polyferrocenylsilane homopolymers and block copolymers

Abstract

Research Groups and Themes

Keywords

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