Abstract
A Lewis basic platinum(0)-CO complex supported by a diphosphine ligand and B(C6F5)3 act cooperatively, in a manner reminiscent of a frustrated Lewis pair, to activate small molecules such as hydrogen, CO2, and ethene. This cooperative Lewis pair facilitates the coupling of CO and ethene in a new way.
Original language | English |
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Pages (from-to) | 2223-2227 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 54 |
Issue number | 7 |
DOIs | |
Publication status | Published - 9 Feb 2015 |
Structured keywords
- BCS and TECS CDTs
Keywords
- Cooperative effects
- Frustrated Lewis pairs
- Small molecule activation
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Dive into the research topics of 'Cooperative Lewis pairs based on late transition metals: Activation of small molecules by platinum(0) and B(C6F5)3'. Together they form a unique fingerprint.Profiles
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Dr Natalie Fey
- School of Chemistry - Associate Professor
- Synthesis
- Supramolecular and Mechanistic Chemistry
- Catalysis
- Computational and Theoretical Chemistry
Person: Academic , Member
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Professor Paul G Pringle
- Synthesis
- Catalysis
- School of Chemistry - Professor of Inorganic Chemistry
Person: Academic , Member