TY - JOUR
T1 - Cooperative Lewis pairs based on late transition metals
T2 - Activation of small molecules by platinum(0) and B(C6F5)3
AU - Forrest, Sebastian J K
AU - Clifton, Jamie
AU - Fey, Natalie
AU - Pringle, Paul G.
AU - Sparkes, Hazel A.
AU - Wass, Duncan F.
PY - 2015/2/9
Y1 - 2015/2/9
N2 - A Lewis basic platinum(0)-CO complex supported by a diphosphine ligand and B(C6F5)3 act cooperatively, in a manner reminiscent of a frustrated Lewis pair, to activate small molecules such as hydrogen, CO2, and ethene. This cooperative Lewis pair facilitates the coupling of CO and ethene in a new way.
AB - A Lewis basic platinum(0)-CO complex supported by a diphosphine ligand and B(C6F5)3 act cooperatively, in a manner reminiscent of a frustrated Lewis pair, to activate small molecules such as hydrogen, CO2, and ethene. This cooperative Lewis pair facilitates the coupling of CO and ethene in a new way.
KW - Cooperative effects
KW - Frustrated Lewis pairs
KW - Small molecule activation
UR - http://www.scopus.com/inward/record.url?scp=84922374518&partnerID=8YFLogxK
U2 - 10.1002/anie.201409872
DO - 10.1002/anie.201409872
M3 - Article (Academic Journal)
C2 - 25538001
AN - SCOPUS:84922374518
SN - 1433-7851
VL - 54
SP - 2223
EP - 2227
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 7
ER -
