TY - JOUR
T1 - Coordination compounds from the planar tridentate Schiff-base ligand 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH) with several transition metal ions
T2 - Use of [FeIII(mqmp)(CH3OH)Cl2] in the catalytic oxidation of alkanes and alkenes
AU - Nayak, Sanjit
AU - Gamez, Patrick
AU - Kozlevcar, Bojan
AU - Pevec, Andrej
AU - Roubeau, Olivier
AU - Dehnen, Stefanie
AU - Reedijk, Jan
N1 - Publisher Copyright:
© 2010 Elsevier Ltd. All rights reserved.
PY - 2010/7/28
Y1 - 2010/7/28
N2 - Four coordination compounds were synthesized in high yields from different transition metal ions (FeIII, CoII, and CuII) and an in situ generated Schiff-base ligand, i.e. 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH). The compounds were characterized by single-crystal X-ray diffraction, ESI-MS, IR spectroscopy, and ligand-field spectroscopy. The iron(III) complex is an efficient catalyst for the oxidation of alkanes and alkenes, under relatively mild conditions and with dihydrogen peroxide as terminal oxidant.
AB - Four coordination compounds were synthesized in high yields from different transition metal ions (FeIII, CoII, and CuII) and an in situ generated Schiff-base ligand, i.e. 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH). The compounds were characterized by single-crystal X-ray diffraction, ESI-MS, IR spectroscopy, and ligand-field spectroscopy. The iron(III) complex is an efficient catalyst for the oxidation of alkanes and alkenes, under relatively mild conditions and with dihydrogen peroxide as terminal oxidant.
U2 - 10.1016/j.poly.2010.04.035
DO - 10.1016/j.poly.2010.04.035
M3 - Article (Academic Journal)
SN - 0277-5387
VL - 29
SP - 2291
EP - 2296
JO - Polyhedron
JF - Polyhedron
IS - 11
ER -