Coordination compounds from the planar tridentate Schiff-base ligand 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH) with several transition metal ions: Use of [FeIII(mqmp)(CH3OH)Cl2] in the catalytic oxidation of alkanes and alkenes

Sanjit  Nayak; Patrick Gamez; Bojan  Kozlevcar; Andrej  Pevec; Olivier  Roubeau; Stefanie  Dehnen; Jan Reedijk

doi:10.1016/j.poly.2010.04.035

Coordination compounds from the planar tridentate Schiff-base ligand 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH) with several transition metal ions: Use of [Fe^III(mqmp)(CH₃OH)Cl₂] in the catalytic oxidation of alkanes and alkenes

Sanjit Nayak
, Patrick Gamez
, Bojan Kozlevcar
, Andrej Pevec
, Olivier Roubeau
, Stefanie Dehnen
, Jan Reedijk^*

^*Corresponding author for this work

School of Civil, Aerospace and Design Engineering

Research output: Contribution to journal › Article (Academic Journal) › peer-review

63 Citations (Scopus)

Abstract

Four coordination compounds were synthesized in high yields from different transition metal ions (Fe^III, Co^II, and Cu^II) and an in situ generated Schiff-base ligand, i.e. 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH). The compounds were characterized by single-crystal X-ray diffraction, ESI-MS, IR spectroscopy, and ligand-field spectroscopy. The iron(III) complex is an efficient catalyst for the oxidation of alkanes and alkenes, under relatively mild conditions and with dihydrogen peroxide as terminal oxidant.

Original language	English
Pages (from-to)	2291-2296
Number of pages	6
Journal	Polyhedron
Volume	29
Issue number	11
Early online date	23 May 2010
DOIs	https://doi.org/10.1016/j.poly.2010.04.035
Publication status	Published - 28 Jul 2010

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Nayak, S., Gamez, P., Kozlevcar, B., Pevec, A., Roubeau, O., Dehnen, S., & Reedijk, J. (2010). Coordination compounds from the planar tridentate Schiff-base ligand 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH) with several transition metal ions: Use of [Fe^III(mqmp)(CH₃OH)Cl₂] in the catalytic oxidation of alkanes and alkenes. Polyhedron, 29(11), 2291-2296. https://doi.org/10.1016/j.poly.2010.04.035

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title = "Coordination compounds from the planar tridentate Schiff-base ligand 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH) with several transition metal ions: Use of [FeIII(mqmp)(CH3OH)Cl2] in the catalytic oxidation of alkanes and alkenes",

abstract = "Four coordination compounds were synthesized in high yields from different transition metal ions (FeIII, CoII, and CuII) and an in situ generated Schiff-base ligand, i.e. 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH). The compounds were characterized by single-crystal X-ray diffraction, ESI-MS, IR spectroscopy, and ligand-field spectroscopy. The iron(III) complex is an efficient catalyst for the oxidation of alkanes and alkenes, under relatively mild conditions and with dihydrogen peroxide as terminal oxidant.",

author = "Sanjit Nayak and Patrick Gamez and Bojan Kozlevcar and Andrej Pevec and Olivier Roubeau and Stefanie Dehnen and Jan Reedijk",

year = "2010",

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Nayak, S, Gamez, P, Kozlevcar, B, Pevec, A, Roubeau, O, Dehnen, S & Reedijk, J 2010, 'Coordination compounds from the planar tridentate Schiff-base ligand 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH) with several transition metal ions: Use of [Fe^III(mqmp)(CH₃OH)Cl₂] in the catalytic oxidation of alkanes and alkenes', Polyhedron, vol. 29, no. 11, pp. 2291-2296. https://doi.org/10.1016/j.poly.2010.04.035

Coordination compounds from the planar tridentate Schiff-base ligand 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH) with several transition metal ions: Use of [Fe^III(mqmp)(CH₃OH)Cl₂] in the catalytic oxidation of alkanes and alkenes. / Nayak, Sanjit ; Gamez, Patrick; Kozlevcar, Bojan et al.
In: Polyhedron, Vol. 29, No. 11, 28.07.2010, p. 2291-2296.

Research output: Contribution to journal › Article (Academic Journal) › peer-review

TY - JOUR

T1 - Coordination compounds from the planar tridentate Schiff-base ligand 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH) with several transition metal ions

T2 - Use of [FeIII(mqmp)(CH3OH)Cl2] in the catalytic oxidation of alkanes and alkenes

AU - Nayak, Sanjit

AU - Gamez, Patrick

AU - Kozlevcar, Bojan

AU - Pevec, Andrej

AU - Roubeau, Olivier

AU - Dehnen, Stefanie

AU - Reedijk, Jan

PY - 2010/7/28

Y1 - 2010/7/28

N2 - Four coordination compounds were synthesized in high yields from different transition metal ions (FeIII, CoII, and CuII) and an in situ generated Schiff-base ligand, i.e. 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH). The compounds were characterized by single-crystal X-ray diffraction, ESI-MS, IR spectroscopy, and ligand-field spectroscopy. The iron(III) complex is an efficient catalyst for the oxidation of alkanes and alkenes, under relatively mild conditions and with dihydrogen peroxide as terminal oxidant.

AB - Four coordination compounds were synthesized in high yields from different transition metal ions (FeIII, CoII, and CuII) and an in situ generated Schiff-base ligand, i.e. 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH). The compounds were characterized by single-crystal X-ray diffraction, ESI-MS, IR spectroscopy, and ligand-field spectroscopy. The iron(III) complex is an efficient catalyst for the oxidation of alkanes and alkenes, under relatively mild conditions and with dihydrogen peroxide as terminal oxidant.

U2 - 10.1016/j.poly.2010.04.035

DO - 10.1016/j.poly.2010.04.035

M3 - Article (Academic Journal)

SN - 0277-5387

VL - 29

SP - 2291

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JO - Polyhedron

JF - Polyhedron

IS - 11

ER -

Nayak S, Gamez P, Kozlevcar B, Pevec A, Roubeau O, Dehnen S et al. Coordination compounds from the planar tridentate Schiff-base ligand 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH) with several transition metal ions: Use of [Fe^III(mqmp)(CH₃OH)Cl₂] in the catalytic oxidation of alkanes and alkenes. Polyhedron. 2010 Jul 28;29(11):2291-2296. Epub 2010 May 23. doi: 10.1016/j.poly.2010.04.035