Crosslinked Porous Polyimides: Structure, Properties and Applications

Basiram Brahma Narzary; Benjamin C. Baker; Neha Yadav; Valerio  D’Elia; Charl F J Faul

doi:10.1039/d1py00997d

Crosslinked Porous Polyimides: Structure, Properties and Applications

Basiram Brahma Narzary, Benjamin C. Baker, Neha Yadav, Valerio D’Elia, Charl F J Faul

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

Abstract

Porous Polyimides (pPIs) represent a fascinating class of porous organic polymers (POPs). Not only do they exhibit high thermal and chemical stabilities, high surface areas, and energy storage capabilities, but their formation relies upon simple polycondensation reactions. A wide library of linker (dianhydrides) and core (amines) starting materials offer a vast range of crosslinked pPIs. This review details and carefully compares the unique properties and functions of both amorphous and crystalline pPIs. Furthermore, their applications in current global challenges in the fields of gas storage and separation, electrical energy storage, catalysis, drug delivery and sensors are reported. Finally, the review highlights the progress of pPIs since 2010 and offers an outlook and suggestions for future areas for exploration and potential applications within the field.

Original language	English
Number of pages	21
Journal	Polymer Chemistry
DOIs	https://doi.org/10.1039/d1py00997d
Publication status	Published - 21 Sep 2021

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title = "Crosslinked Porous Polyimides: Structure, Properties and Applications",

abstract = "Porous Polyimides (pPIs) represent a fascinating class of porous organic polymers (POPs). Not only do they exhibit high thermal and chemical stabilities, high surface areas, and energy storage capabilities, but their formation relies upon simple polycondensation reactions. A wide library of linker (dianhydrides) and core (amines) starting materials offer a vast range of crosslinked pPIs. This review details and carefully compares the unique properties and functions of both amorphous and crystalline pPIs. Furthermore, their applications in current global challenges in the fields of gas storage and separation, electrical energy storage, catalysis, drug delivery and sensors are reported. Finally, the review highlights the progress of pPIs since 2010 and offers an outlook and suggestions for future areas for exploration and potential applications within the field.",

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AU - Brahma Narzary, Basiram

AU - Baker, Benjamin C.

AU - Yadav, Neha

AU - D’Elia, Valerio

AU - Faul, Charl F J

PY - 2021/9/21

Y1 - 2021/9/21

N2 - Porous Polyimides (pPIs) represent a fascinating class of porous organic polymers (POPs). Not only do they exhibit high thermal and chemical stabilities, high surface areas, and energy storage capabilities, but their formation relies upon simple polycondensation reactions. A wide library of linker (dianhydrides) and core (amines) starting materials offer a vast range of crosslinked pPIs. This review details and carefully compares the unique properties and functions of both amorphous and crystalline pPIs. Furthermore, their applications in current global challenges in the fields of gas storage and separation, electrical energy storage, catalysis, drug delivery and sensors are reported. Finally, the review highlights the progress of pPIs since 2010 and offers an outlook and suggestions for future areas for exploration and potential applications within the field.

AB - Porous Polyimides (pPIs) represent a fascinating class of porous organic polymers (POPs). Not only do they exhibit high thermal and chemical stabilities, high surface areas, and energy storage capabilities, but their formation relies upon simple polycondensation reactions. A wide library of linker (dianhydrides) and core (amines) starting materials offer a vast range of crosslinked pPIs. This review details and carefully compares the unique properties and functions of both amorphous and crystalline pPIs. Furthermore, their applications in current global challenges in the fields of gas storage and separation, electrical energy storage, catalysis, drug delivery and sensors are reported. Finally, the review highlights the progress of pPIs since 2010 and offers an outlook and suggestions for future areas for exploration and potential applications within the field.

U2 - 10.1039/d1py00997d

DO - 10.1039/d1py00997d

M3 - Article (Academic Journal)

JO - Polymer Chemistry

JF - Polymer Chemistry

SN - 1759-9954

ER -

Crosslinked Porous Polyimides: Structure, Properties and Applications

Abstract

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