Crosslinked Porous Polyimides: Structure, Properties and Applications

Basiram Brahma Narzary; Benjamin C. Baker; Neha Yadav; Valerio  D’Elia; Charl F J Faul

doi:10.1039/d1py00997d

Crosslinked Porous Polyimides: Structure, Properties and Applications

Basiram Brahma Narzary, Benjamin C. Baker, Neha Yadav, Valerio D’Elia, Charl F J Faul

Research output: Contribution to journal › Article (Academic Journal) › peer-review

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Abstract

Porous Polyimides (pPIs) represent a fascinating class of porous organic polymers (POPs). Not only do they exhibit high thermal and chemical stabilities, high surface areas, and energy storage capabilities, but their formation relies upon simple polycondensation reactions. A wide library of linker (dianhydrides) and core (amines) starting materials offer a vast range of crosslinked pPIs. This review details and carefully compares the unique properties and functions of both amorphous and crystalline pPIs. Furthermore, their applications in current global challenges in the fields of gas storage and separation, electrical energy storage, catalysis, drug delivery and sensors are reported. Finally, the review highlights the progress of pPIs since 2010 and offers an outlook and suggestions for future areas for exploration and potential applications within the field.

Original language	English
Pages (from-to)	6494-6514
Number of pages	21
Journal	Polymer Chemistry
Volume	12
Issue number	45
DOIs	https://doi.org/10.1039/d1py00997d
Publication status	Published - 21 Sept 2021

Bibliographical note

Funding Information:
B.B.N acknowledges support from the National Overseas Scholarship for ST Students, Government of India. N. Y. and V. D’E. acknowledge support from Vidyasirimedhi Institute of Science and Technology (VISTEC), Thailand. B. C. B. and C. F. J. F. acknowledge the EPSRC (EP/T020792/1) for support. The authors thank Marcos Villeda Hernandez for graphic design and images.

Publisher Copyright:
© The Royal Society of Chemistry.

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This is the final published version of the article (version of record). It first appeared online via RSC at https://doi.org/10.1039/D1PY00997D . Please refer to any applicable terms of use of the publisher.
Final published version, 2.43 MBLicence: CC BY

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Perylene- and Naphthalene-based Porous Polyimide Networks for CO₂ Capture and Conversion
Brahma Narzary, B. (Author), Faul, C. F. J. (Supervisor), 23 Jan 2024
Student thesis: Doctoral Thesis › Doctor of Philosophy (PhD)

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title = "Crosslinked Porous Polyimides: Structure, Properties and Applications",

abstract = "Porous Polyimides (pPIs) represent a fascinating class of porous organic polymers (POPs). Not only do they exhibit high thermal and chemical stabilities, high surface areas, and energy storage capabilities, but their formation relies upon simple polycondensation reactions. A wide library of linker (dianhydrides) and core (amines) starting materials offer a vast range of crosslinked pPIs. This review details and carefully compares the unique properties and functions of both amorphous and crystalline pPIs. Furthermore, their applications in current global challenges in the fields of gas storage and separation, electrical energy storage, catalysis, drug delivery and sensors are reported. Finally, the review highlights the progress of pPIs since 2010 and offers an outlook and suggestions for future areas for exploration and potential applications within the field.",

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AU - Brahma Narzary, Basiram

AU - Baker, Benjamin C.

AU - Yadav, Neha

AU - D’Elia, Valerio

AU - Faul, Charl F J

N1 - Funding Information: B.B.N acknowledges support from the National Overseas Scholarship for ST Students, Government of India. N. Y. and V. D’E. acknowledge support from Vidyasirimedhi Institute of Science and Technology (VISTEC), Thailand. B. C. B. and C. F. J. F. acknowledge the EPSRC (EP/T020792/1) for support. The authors thank Marcos Villeda Hernandez for graphic design and images. Publisher Copyright: © The Royal Society of Chemistry.

PY - 2021/9/21

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N2 - Porous Polyimides (pPIs) represent a fascinating class of porous organic polymers (POPs). Not only do they exhibit high thermal and chemical stabilities, high surface areas, and energy storage capabilities, but their formation relies upon simple polycondensation reactions. A wide library of linker (dianhydrides) and core (amines) starting materials offer a vast range of crosslinked pPIs. This review details and carefully compares the unique properties and functions of both amorphous and crystalline pPIs. Furthermore, their applications in current global challenges in the fields of gas storage and separation, electrical energy storage, catalysis, drug delivery and sensors are reported. Finally, the review highlights the progress of pPIs since 2010 and offers an outlook and suggestions for future areas for exploration and potential applications within the field.

AB - Porous Polyimides (pPIs) represent a fascinating class of porous organic polymers (POPs). Not only do they exhibit high thermal and chemical stabilities, high surface areas, and energy storage capabilities, but their formation relies upon simple polycondensation reactions. A wide library of linker (dianhydrides) and core (amines) starting materials offer a vast range of crosslinked pPIs. This review details and carefully compares the unique properties and functions of both amorphous and crystalline pPIs. Furthermore, their applications in current global challenges in the fields of gas storage and separation, electrical energy storage, catalysis, drug delivery and sensors are reported. Finally, the review highlights the progress of pPIs since 2010 and offers an outlook and suggestions for future areas for exploration and potential applications within the field.

U2 - 10.1039/d1py00997d

DO - 10.1039/d1py00997d

M3 - Article (Academic Journal)

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VL - 12

SP - 6494

EP - 6514

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 45

ER -

Crosslinked Porous Polyimides: Structure, Properties and Applications

Abstract

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Student theses

Perylene- and Naphthalene-based Porous Polyimide Networks for CO₂ Capture and Conversion

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