Current characterization methods for cellulose nanomaterials

E. Johan Foster*, Robert J. Moon, Umesh P. Agarwal, Michael J. Bortner, Julien Bras, Sandra Camarero-Espinosa, Kathleen J. Chan, Martin J.D. Clift, Emily D. Cranston, Stephen J. Eichhorn, Douglas M. Fox, Wadood Y. Hamad, Laurent Heux, Bruno Jean, Matthew Korey, World Nieh, Kimberly J. Ong, Michael S. Reid, Scott Renneckar, Rose RobertsJo Anne Shatkin, John Simonsen, Kelly Stinson-Bagby, Nandula Wanasekara, Jeff Youngblood

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)

146 Citations (Scopus)

Abstract

A new family of materials comprised of cellulose, cellulose nanomaterials (CNMs), having properties and functionalities distinct from molecular cellulose and wood pulp, is being developed for applications that were once thought impossible for cellulosic materials. Commercialization, paralleled by research in this field, is fueled by the unique combination of characteristics, such as high on-axis stiffness, sustainability, scalability, and mechanical reinforcement of a wide variety of materials, leading to their utility across a broad spectrum of high-performance material applications. However, with this exponential growth in interest/activity, the development of measurement protocols necessary for consistent, reliable and accurate materials characterization has been outpaced. These protocols, developed in the broader research community, are critical for the advancement in understanding, process optimization, and utilization of CNMs in materials development. This review establishes detailed best practices, methods and techniques for characterizing CNM particle morphology, surface chemistry, surface charge, purity, crystallinity, rheological properties, mechanical properties, and toxicity for two distinct forms of CNMs: cellulose nanocrystals and cellulose nanofibrils.

Original languageEnglish
Pages (from-to)2609-2679
Number of pages71
JournalChemical Society Reviews
Volume47
Issue number8
Early online date16 Apr 2018
DOIs
Publication statusPublished - 21 Apr 2018

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Foster, E. J., Moon, R. J., Agarwal, U. P., Bortner, M. J., Bras, J., Camarero-Espinosa, S., Chan, K. J., Clift, M. J. D., Cranston, E. D., Eichhorn, S. J., Fox, D. M., Hamad, W. Y., Heux, L., Jean, B., Korey, M., Nieh, W., Ong, K. J., Reid, M. S., Renneckar, S., ... Youngblood, J. (2018). Current characterization methods for cellulose nanomaterials. Chemical Society Reviews, 47(8), 2609-2679. https://doi.org/10.1039/C6CS00895J, https://doi.org/10.1039/c6cs00895j