Data report: X-ray fluorescence scanning of sediment cores, IODP Expedition 401 Site U1610, Gulf of Cádiz, Atlantic

Xunhui Xu*, Jonathan Stine, Patricia Standring, Francisco Javier Hernández-Molina, Isabelle Billy, Shamar Chin, Sarah J. Feakins, Zhiyang Li, Madeline Mulligan, Danielle Noto, Fadl Raad, Manuel Teixeira, Jesse Yeon, Mohamed Zakaria Yousfi, Yunlang Zhang, Rachel Flecker, Emmanuelle Ducassou, Trevor Williams, Expedition 401 Scientists

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

Abstract

International Ocean Discovery Program (IODP) Expedition 401 recovered sediment cores from Site U1610, located in the Gulf of Cádiz. This report presents semiquantitative chemical results based on high-resolution (5 cm) X-ray fluorescence (XRF) scanning of Hole U1610A Miocene to Pliocene core sections from 4.5 to 6 Ma (651–1026 m core depth below seafloor, Method A [CSF-A]). Processed element intensities (counts per second) of Al, Si, Ti, Fe, Rb, Ca, Sr, Zr, Mn, and Ba are discussed. XRF results are divided into four units with depth according to the amplitude and wavelength of cyclicities, among which clear cyclicities with 4–7 m wavelengths are observed in Unit 1. Unit 3 and the upper part of Unit 4 (middle Messinian Salinity Crisis [MSC]) have higher amplitude cyclicity, and Unit 2 (close to the Miocene/Pliocene boundary) and the lower part of Unit 4 (early MSC) have the lowest amplitude signals. The most pronounced spikes of XRF and physical properties occur in the middle of the MSC and at the onset of the MSC. Additionally, this report discusses the implications regarding terrigenous versus biogenic components. There are positive correlations between terrigenous elements (Al, Si, and Ti), but generally weak negative correlations dominate between these terrigenous elements and biogenic elements (Ca and Sr). This high-resolution data set, in conjunction with other data sets produced from Expedition 401, will help with the interpretation of the sedimentary processes and paleoclimate changes impacting the Gulf of Cádiz before, during, and after the MSC.
Original languageEnglish
Number of pages8
JournalProceedings of the International Ocean Discovery Program
Volume401
DOIs
Publication statusPublished - 12 Feb 2026

Keywords

  • Expedition 401
  • IODP
  • International Ocean Discovery Program
  • JOIDES Resolution
  • Mediterranean Outflow Water
  • Mediterranean–Atlantic Gateway Exchange
  • Messinian Salinity Crisis
  • Site U1610

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