Dearomatising rearrangements of lithiated thiophenecarboxamides

Jonathan Clayden*, Rachel Turnbull, Madeleine Helliwell, Ivan Pinto

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

21 Citations (Scopus)

Abstract

Thiophene-3-carboxamides bearing allyl or benzyl substituents at nitrogen undergo dearomatising cyclisation on treatment with LDA. Rearrangements transform the dearomatised products into pyrrolinones, azepinones or partially saturated azepinothiophenes.

Original languageEnglish
Pages (from-to)2430-2431
Number of pages2
JournalChemical Communications
Volume10
Issue number21
Early online date22 Sep 2004
DOIs
Publication statusPublished - 7 Nov 2004

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