Dearomatization and Aryl Migration in Organolithium Chemistry

Jonathan Clayden

doi:10.1002/9783527667512.ch13

Dearomatization and Aryl Migration in Organolithium Chemistry

Jonathan Clayden^*

^*Corresponding author for this work

School of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter in a book

3 Citations (Scopus)

Abstract

Nucleophilic addition of organolithiums to electron-rich π systems such as aromatic rings or alkenes can lead either to dearomatizing cyclization, to carbolithiation, or to aryl or alkenyl migration. The development and application of these reactions during the 15 years between 1998 and 2013 are discussed in this chapter.

Original language	English
Title of host publication	Lithium Compounds in Organic Synthesis: From Fundamentals to Applications
Publisher	Wiley-Blackwell
Pages	375-396
Number of pages	22
ISBN (Print)	9783527667512, 9783527333431
DOIs	https://doi.org/10.1002/9783527667512.ch13
Publication status	Published - 19 May 2014

Keywords

Addition reaction
Aryl migration
Cyclization
Dearomatization
Heterocycle
Organolithium

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10.1002/9783527667512.ch13

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title = "Dearomatization and Aryl Migration in Organolithium Chemistry",

abstract = "Nucleophilic addition of organolithiums to electron-rich π systems such as aromatic rings or alkenes can lead either to dearomatizing cyclization, to carbolithiation, or to aryl or alkenyl migration. The development and application of these reactions during the 15 years between 1998 and 2013 are discussed in this chapter.",

keywords = "Addition reaction, Aryl migration, Cyclization, Dearomatization, Heterocycle, Organolithium",

author = "Jonathan Clayden",

year = "2014",

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AU - Clayden, Jonathan

PY - 2014/5/19

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N2 - Nucleophilic addition of organolithiums to electron-rich π systems such as aromatic rings or alkenes can lead either to dearomatizing cyclization, to carbolithiation, or to aryl or alkenyl migration. The development and application of these reactions during the 15 years between 1998 and 2013 are discussed in this chapter.

AB - Nucleophilic addition of organolithiums to electron-rich π systems such as aromatic rings or alkenes can lead either to dearomatizing cyclization, to carbolithiation, or to aryl or alkenyl migration. The development and application of these reactions during the 15 years between 1998 and 2013 are discussed in this chapter.

KW - Addition reaction

KW - Aryl migration

KW - Cyclization

KW - Dearomatization

KW - Heterocycle

KW - Organolithium

UR - http://www.scopus.com/inward/record.url?scp=84927109110&partnerID=8YFLogxK

U2 - 10.1002/9783527667512.ch13

DO - 10.1002/9783527667512.ch13

M3 - Chapter in a book

AN - SCOPUS:84927109110

SN - 9783527667512

SN - 9783527333431

SP - 375

EP - 396

BT - Lithium Compounds in Organic Synthesis: From Fundamentals to Applications

PB - Wiley-Blackwell

ER -

Dearomatization and Aryl Migration in Organolithium Chemistry

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Keywords

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