Diastereodivergent Synthesis of Trisubstituted Alkenes through Protodeboronation of Allylic Boronic Esters: Application to the Synthesis of the Californian Red Scale Beetle Pheromone

Matthew J. Hesse, Craig P. Butts, Christine L. Willis*, Varinder K. Aggarwal

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

43 Citations (Scopus)
Original languageEnglish
Pages (from-to)12444-12448
Number of pages5
JournalAngewandte Chemie - International Edition
Volume51
Issue number50
DOIs
Publication statusPublished - 2012

Structured keywords

  • BCS and TECS CDTs

Keywords

  • HIGHLY STEREOSELECTIVE-SYNTHESIS
  • diastereoselectivity
  • allylic compounds
  • natural products
  • ALCOHOLS
  • STEREOSPECIFIC SYNTHESIS
  • protodeboronation
  • BORYLATION
  • SEX-PHEROMONE
  • OLEFINATION REACTION
  • SELECTIVITY
  • alkenes
  • CONVERSION
  • ALDEHYDES
  • REARRANGEMENT

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